Electron spin relaxation times T and T of Tb and Tm in 1:1 water:ethanol and of Tb doped (2%) in crystalline La(oxalate) decahydrate were measured between about 4.2 and 10 K. Both cations are non-Kramers ions and have J = 6 ground states.
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May 2019
The structural features leading to the intense quenching free luminescence exhibited by europium oxalate nanocrystals, poly[[hexaaquatri-μ-oxalato-dieuropium] 4.34-hydrate], {[Eu(CO)(HO)]·4.34HO}, is the focal point of this report.
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