Sophisticated structure design and multi-step manufacturing processes for balancing spectra-selective optical property and the necessary applicable performance for human thermal-wet regulation, is the major limitation in wide application of radiative cooling materials. Herein, we proposed a biomass confinement strategy to a gradient porous Janus cellulose film for enhanced optical performance without compromising thermal-wet comfortable. The bacterial cellulose confined grow in the micro-nano pores between PP nonwoven fabric and SiO achieving the cross-scale gradient porous Janus structure.
View Article and Find Full Text PDFIn nature, spider web is an interwoven network with high stability and elasticity from silk threads secreted by spider. Inspired by the structure of spider webs, light-driven liquid crystal elastomer (LCE) active yarn is designed with super-contractile and robust weavability. Herein, a novel biomimetic gold nanorods (AuNRs) @LCE yarn soft actuator with hierarchical structure is fabricated by a facile electrospinning and subsequent photocrosslinking strategies.
View Article and Find Full Text PDFLiquid crystal elastomers (LCEs) are a kind of polymer network that combines the entropic elasticity of polymer networks and the mesogenic unit by means of mild cross-linking. LCEs have been extensively investigated in various fields, including artificial muscles, actuators, and microrobots. However, LCEs are characterized by the poor mechanical properties of the light polymers themselves.
View Article and Find Full Text PDFDue to the overuse of antimicrobial drugs, bacterial resistance became an urgent problem to be solved. In this study, carbon quantum dots (CQDs) with high photodynamic antibacterial activity were synthesized by a one-pot hydrothermal method and introduced into bacterial cellulose (BC) dispersion solution. Through a wet-spinning and wet-twisting processing strategy, bionic ordering nanocomposite macrofiber (BC/CQDs-based yarn) based on BC were obtained.
View Article and Find Full Text PDFLiquid crystal elastomer (LCE) fibers exhibit large deformation and reversibility, making them an ideal candidate for soft actuators. It is still challenging to develop a scalable strategy and endow fiber actuators with photoelectric functions to achieve tailorable photo-electro-thermal responsiveness and rapid large actuation deformation. Herein, we fabricated a multiresponsive actuator that consists of LCE long fibers obtained by continuous dry spinning and further coated it with polydopamine (PDA)-modified MXene ink.
View Article and Find Full Text PDFEnzyme membrane systems (EMS) have generated considerable interest because of their advantages of accelerating reactions, eliminating product inhibition, and enhancing conversion rates. However, there are deficiencies in the efficient fabrication of affinity carrier membranes and dynamic catalytic separation properties. Herein, a strong and highly flexible spunlaced viscose/bacterial cellulose (BC) composite membrane in situ embedded with graphene oxide (GO) was developed by combining a scalable bio-synthesis method with atom transfer radical polymerization technology.
View Article and Find Full Text PDFLaccase is a promising biocatalyst for pollutant degradation and water purification. However, laccase can only improve the stability of enzyme activity and achieve its significant catalytic effect after effective immobilization. Herein, we report a general strategy to integrate nanocellulose aerogel and laccase for high-efficiency degradation of organic pollutants.
View Article and Find Full Text PDFIt is necessary to effectively separate photocatalytic materials from water bodies and reuse catalysts for industrial wastewater treatment. Herein, a novel nanofiber membrane with enhanced light absorption and reusability of photocatalytic materials was prepared. The three-dimensional porous structure of the nanofibers helps the photocatalyst efficiently degrade pollutants.
View Article and Find Full Text PDFTo date, the preparation of a novel ultrafiltration membrane and the efficient separation and purification of protein solutions have gradually attracted widespread attention of many researchers. In this study, a hollow porous polystyrene/ethylene-vinyl acetate copolymer blend nanofibrous membrane (PS/EVA-BNM) was generated by electrospinning and chemical modification and then used to separate and purify proteins in solution. The BNM was characterized by scanning electron microscopy and specific surface area and pore size analyses.
View Article and Find Full Text PDFIn this study, an innovative nano-material was prepared, which was ultilized to removal of heavy metal ions from wastewater. Polyacrylonitrile/cellulose acetate (PAN/CA) composite nanofibrous membranes were generated by the electronspinning technique first, and then amidoxime ployarcylonitrile/regenerate cellulose (AOPAN/RC) composite nanofibrous membranes were prepared by combining hydrolysis and amidoximation modification. The modification of composite nanofibers (AOPAN/RC) were consequently used in heavy metal ions adsorption.
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