Mechanistic insight into confined Fenton system in the MXene layer (MXene-Fe@PES) for enhanced aquatic contaminant removal.

The confinement strategy was considered as an effective method for enhanced aquatic contaminant removal in catalytic systems, and the two-dimensional (2D) material displayed sufficient capacities for contaminant attenuation as compared to other materials due to the unique interlayer structures. However, information on the construction of confined catalytic systems using 2D materials is still lacked. Here, a novel 2D catalytic system in which Fe atoms were illustrated into MXene layers and polyether sulfone (PES) substrate (named MXene-Fe@PES) was established to explore its degradation potential toward typical aquatic contaminants e.

Controlled Construction of Cu(I) Sites within Confined Spaces via Host-Guest Redox: Highly Efficient Adsorbents for Selective CO Adsorption.

Here, we designed a double-solvent/host-guest redox combined strategy to construct Cu sites in metal-organic frameworks (MOFs) for the first time. As a proof of concept, a representative MOF MIL-100(Fe) with tunable valence states of cations was employed as the host. The combined strategy realizes selective introduction of Cu precursors to the interior pores of MIL-100(Fe), remarkably minimizing the aggregation of Cu and subsequently formed Cu species.

Unusual ceria dispersion formed in confined space: a stable and reusable adsorbent for aromatic sulfur capture.

An unusual ceria dispersion was achieved by using the confined space between template and silica walls in as-prepared mesoporous silica, for the first time. The new adsorbents exhibit high adsorptive desulfurization activity and, more importantly, excellent stability and reusability, which is impossible to realize with conventional adsorbents.