SiC/Al-Fe-V-Si composites exhibit complex deformation behaviors at both room and high temperatures because of the presence of SiC reinforcement particles and numerous fine dispersed Al(Fe, V)Si heat-resistant phases. In this work, an artificial neural network (ANN) constitutive model was established to study the deformation behavior of SiC/Al-7.75Fe-1.
View Article and Find Full Text PDFSiC particle (SiCp) size has been found to significantly influence the hot workability of particle-reinforced aluminum matrix composites (AMC). In this work, therefore, three types of SiCp/6013 composites with different SiCp sizes (0.7, 5 and 15 μm) were prepared and then subjected to isothermal hot compression tests.
View Article and Find Full Text PDFThe size and distribution of ceramic particles in aluminum matrix composites have been reported to remarkably influence their properties. For a single ceramic particle, the particle size is too small and prone to agglomeration, which makes the mechanical properties of the composites worse. When the ceramic particle size is too large, the particles and alloy at the interface are not firmly bonded, and the effect of dispersion distribution is not achieved, which will also reduce the mechanical properties of the composites.
View Article and Find Full Text PDFGrain size is a microscopic parameter that has a significant impact on the macroscopic deformation behavior and mechanical properties of twinning induced plasticity (TWIP) steels. In this study, Fe-18Mn-1.3Al-0.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
June 2022
SignificanceThe present work might be significant for exploring advanced K-ion batteries with superb rate capability and cycle stability toward practical applications. The as-assembled K-ion half cell exhibits an excellent rate capability of 428 mA h g at 100 mA g and a high reversible specific capacity of 330 mA h g with 120% specific capacity retention after 2,000 cycles at 2,000 mA g, which is the best among those based on carbon materials. The as-constructed full cell delivers 98% specific capacity retention over 750 cycles at 500 mA g, superior to most of those based on carbon materials that have been reported thus far.
View Article and Find Full Text PDFMagnesium-rare earth (Mg-Re) alloys are very promising structural materials in lightweight industries, while the poor corrosion resistance limits their widespread application. In this work, to provide insights into the functions of precipitate characteristics on the corrosion behaviors of Mg-Re alloys, the influence of heat treatments on the corrosion behavior of Mg-11.46Gd-4.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2021
Currently, a big challenge for the practical use of potassium-ion batteries (PIBs) is their intrinsically poor cycling stability, due to the relatively large radius of K and sluggish kinetics for intercalation/deintercalation. Here we report the scalable fabrication of N/S-codoped hollow carbon nanocubes (NSHCCs), which have the potential as an electrode for advanced PIBs with robust stability. Their discharge and charge specific capacities are ∼560 mA h g and 310 mA h g at a current density of 50 mA g, respectively.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
August 2021
The popularly reported energy storage mechanisms of potassium-ion batteries (PIBs) are based on alloy-, de-intercalation-, and conversion-type processes, which inevitably lead to structural damage of the electrodes caused by intercalation/de-intercalation of K with a relatively large radius, which is accompanied by poor cycle stabilities. Here, we report the exploration of robust high-temperature PIBs enabled by a carboxyl functional group energy storage mechanism, which is based on an example of p-phthalic acid (PTA) with two carboxyl functional groups as the redox centers. In such a case, the intercalation/de-intercalation of K can be performed via surface reactions with relieved volume change, thus favoring excellent cycle stability for PIBs against high temperatures.
View Article and Find Full Text PDFPhotoelectrochemical (PEC) splitting of water into H and O by direct use of sunlight is an ideal strategy for the production of clean and renewable energy, which fundamentally relies on the exploration of advanced photoanodes with high performance. In the present work, we report that single-crystal integrated photoanodes, that is, 4-SiC nanohole arrays (active materials) and SiC wafer substrate (current collector), are established into a totally single-crystal configuration without interfaces, which was based on a two-step electrochemical etching process. The as-fabricated SiC photoanode showed a rather low onset potential of -0.
View Article and Find Full Text PDFIn the present work, the exploration of photodetectors (PDs) based on CsPbI nanotubes are reported. The as-prepared CsPbI nanotubes can be stable for more than 2 months under air conditions. It is found that, in comparison to the nanowires, nanobelts, and nanosheets, the nanotubes can be advantageous to be used as the functional units for PDs, which is mainly attributed to the enhanced light absorption ability induced by the light trapping effect within the tube cavity.
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