Molecular Iron Oxide Clusters Boost the Oxygen Reduction Reaction of Platinum Electrocatalysts at Near-Neutral pH.

The oxygen reduction reaction (ORR) is a key energy conversion process, which is critical for the efficient operation of fuel cells and metal-air batteries. Here, we report the significant enhancement of the ORR-performance of commercial platinum-on-carbon electrocatalysts when operated in aqueous electrolyte solutions (pH 5.6), containing the polyoxoanion [Fe (μ -O) (L-(-)-tart) (CH COO) ] .

Cyclic voltammetry electrodeposition of well-dispersed Pd nanoparticles on carbon paper as a flow-through anode for microfluidic direct formate fuel cells.

The preparation of low-loading and high-performance Pd-based electrodes is required for direct formate fuel cells. In this study, cyclic voltammetry electrodeposition is used to electrodeposit Pd nanoparticles on carbon paper (Pd/CP) and achieve excellent activity and promising stability toward the formate oxidation reaction (FOR). The prepared electrode shows a thin layer of hemispherical and well-dispersed Pd nanoparticles on the fibers of the carbon paper.

Uneven biofilm and current distribution in three-dimensional macroporous anodes of bio-electrochemical systems composed of graphite electrode arrays.

A 3-D macroporous anode was constructed using different numbers of graphite rod arrays in fixed-volume bio-electrochemical systems (BESs), and the current and biofilm distribution were investigated by dividing the 3-D anode into several subunits. In the fixed-volume chamber, current production was not significantly improved after the electrode number increased to 36. In the case of 100 electrodes, a significant uneven current distribution was found in the macroporous anode.

Anolyte recirculation effects in buffered and unbuffered single-chamber air-cathode microbial fuel cells.

Two identical microbial fuel cells (MFCs) with a floating air-cathode were operated under either buffered (MFC-B) or bufferless (MFC-BL) conditions to investigate anolyte recirculation effects on enhancing proton transfer. With an external resistance of 50 Ω and recirculation rate of 1.0 ml/min, MFC-BL had a 27% lower voltage (9.