Photoenhanced intrinsic peroxidase-like activity of a metal-free biocompatible borophene photonanozyme for colorimetric sensor assay of dopamine biomolecule.

Photonanozymes are novel enzyme-mimicking nanomaterials with light-harvesting capacity and have widespread applications in many areas including biosensing, biomedicine, environmental applications, energy, Herein, we introduce freestanding metal-free biocompitable borophene nanosheets (BNSs) exhibiting excellent photoresponsive peroxidase-like activity for biosensing applications. The photo-enhanced peroxidase-like activity of BNSs photonanozyme was indicated to be due to its band gap energy being comparable to the energy of visible light.

Atomically Dispersed Manganese on Graphene Nanosheets as Biocompatible Nanozyme for Glutathione Detection in Liver Tissue Lysate Using Microfluidic Paper-based Analytical Devices.

Recently, single atom catalysts (SACs) featuring M-N (M = metal) active sites on carbon support have drawn considerable attention due to their promising enzyme-like catalytic properties. However, typical synthesis methods of SACs often involve energy-intensive carbonization processes. Herein, we report a facile one-pot, low-temperature, wet impregnation method to fully utilize M-N sites of manganese phthalocyanine (MnPc) by decorating molecular MnPc over the sheets of graphene nanoplatelets (GNP).