Waveguides have been utilized for label-free and miniaturized mid-infrared gas sensors that operate on the evanescent field absorption principle. For integrated systems, photodetectors based on the photocarrier generation principle are previously integrated with waveguides. However, due to the thermal excitation of carriers at room temperature, they suffer from large dark currents and noise in the long-wavelength region.
View Article and Find Full Text PDFMiniaturized infrared spectroscopy is highly desired for widespread applications, including environment monitoring, chemical analysis, and biosensing. Nanoantennas, as a promising approach, feature strong field enhancement and provide opportunities for ultrasensitive molecule detection even in the nanoscale range. However, current efforts for higher sensitivities by nanogaps usually suffer a trade-off between the performance and fabrication cost.
View Article and Find Full Text PDFAluminum nitride on insulator (AlNOI) photonics platform has great potential for mid-infrared applications thanks to the large transparency window, piezoelectric property, and second-order nonlinearity of AlN. However, the deployment of AlNOI platform might be hindered by the high propagation loss. We perform thermal annealing study and demonstrate significant loss improvement in the mid-infrared AlNOI photonics platform.
View Article and Find Full Text PDFWe report an aluminum nitride on insulator platform for mid-infrared (MIR) photonics applications beyond 3 μm. Propagation loss and bending loss are studied, while functional devices such as directional couplers, multimode interferometers, and add/drop filters are demonstrated with high performance. The complementary metal-oxide-semiconductor-compatible aluminum nitride offers advantages ranging from a large transparency window, high thermal and chemical resistance, to piezoelectric tunability and three-dimensional integration capability.
View Article and Find Full Text PDFACS Appl Mater Interfaces
November 2018
The surface-enhanced infrared absorption (SEIRA) technique has been focusing on the metallic resonator structures for decades, exploring different approaches to enhance sensitivity. Although the high enhancement is achieved, the dissipative loss and strong heating are the intrinsic drawbacks of metals. Recently, the dielectric platform has emerged as a promising alternative.
View Article and Find Full Text PDFApplication of two major classes of CO gas sensors, i.e., electrochemical and nondispersive infrared is predominantly impeded by the poor selectivity and large optical interaction length, respectively.
View Article and Find Full Text PDFPhotodetectors with broadband detection capability are desirable for sensing applications in the coming age of the internet-of-things. Although 2D layered materials (2DMs) have been actively pursued due to their unique optical properties, by far only graphene and black arsenic phosphorus have the wide absorption spectrum that covers most molecular vibrational fingerprints. However, their reported responsivity and response time are falling short of the requirements needed for enabling simultaneous weak-signal and high-speed detections.
View Article and Find Full Text PDFA water-air triboelectric nanogenerator (WATENG) is presented for CO sensing application. During the operation of WATENG, two independent charge transfers can be used to characterize the effect of force and humidity, respectively. Thus, the structure of WATENG provides a capability to eliminate these two major interferences in a triboelectric self-powered sensor.
View Article and Find Full Text PDFWe use a paradigmatic mathematic model known as fractal to reverse-engineer artificial nanostructures that can potentially serve as plasmonic metasurfaces as well as nanogap electrodes. Herein, we particularly demonstrate the possibility of obtaining multispectral extraordinary optical transmission-like transmission peaks from fractal-inspired geometries, which can preserve distinct spatial characteristics. To achieve enhanced volumetric interaction and thermal responsiveness within the framework, we consider a bilayer, quasi-three-dimensional (3D) configuration that relies on the unique approach of combining complementary and noncomplementary surfaces, while avoiding the need for multilayer alignment on the nanoscale.
View Article and Find Full Text PDFWe report the first thermal study of a triple band plasmonic nanoantenna strongly coupled to a molecular mode at mid IR wavelength (MW IR). The hybrid plasmonic structure supports three spatially and spectrally variant resonances of which two are magnetic and one is dipolar in nature. A hybridized mode is excited by coupling the structure's plasmonic mode with the vibrational mode of PMMA at 5.
View Article and Find Full Text PDFWe demonstrate a surface enhanced Raman scattering (SERS) substrate by integrating plasmonic-active SiO(2) nanotubes into Si(3)N(4) gratings. First, the dielectric grating that is working under guided mode resonance (GMR) provides enhanced electric field for localized surface plasmon polaritons on the surface of metallic nanoparticles. Second, we use SiO(2) nanotubes with densely assembled silver nanoparticles to provide a large amount of "hot spots" without significantly damping the GMR mode of the grating.
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