Publications by authors named "Dickey M"

To quantify how the viscosities of silicone oil (SO) and liquid metal (LM) relate to emulsion-formation (LM-in-SO SO-in-LM), a process was developed to produce LM pastes with adjustable viscosity and minimal oxide and bubbles. Increased LM viscosity allows greater silicone oil intake and/or intake of higher-viscosity silicone oils.

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  • Communication technologies expose us to electromagnetic fields (EMF), which may pose health risks, especially for vulnerable groups like pregnant women.
  • We developed a triboelectric ferrofluid fiber (TFF) that can detect EMF and generates its own charge, making it flexible and suitable for integration into fabrics.
  • This smart fabric can provide environmental warnings and real-time health monitoring, specifically designed for the safety and healthcare needs of at-risk populations.
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Background: Stressful large-scale events, such as the COVID-19 pandemic and natural disasters, impact birthing individuals' postpartum experiences and their mental health. Resultant changes in government assistance, housing, and employment may further exacerbate these impacts, with differences experienced by varying income levels and races. This study aimed to examine maternal depression and anxiety in postpartum individuals by income and race during a stressful large-scale event, and the mediating role of government assistance, housing, and employment.

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  • Native oxides significantly reduce the surface tension of gallium-based liquid metal alloys, dropping it from 724 to 10 mN/m, making them effective like surfactants.
  • Unlike traditional surfactants, native oxides naturally form on metals and are much more efficient at lowering surface tension, facilitating better adhesion to surfaces.
  • The unique interfacial properties of these oxides not only stabilize liquid metal structures but also enable the creation of oxide-filled bubbles and thin oxide films, with potential applications across various metals and their oxides.
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  • Early life stress (ELS) in mice leads to cognitive issues and changes in dopamine receptor expression in the male offspring's anterior cingulate cortex (ACC).
  • Fragmented maternal care during a critical neonatal period resulted in elevated D2R and suppressed D4R, impairing performance on visual attention tasks, but this could be reversed in adulthood through pharmacological interventions.
  • ELS male mice also exhibited increased hypothalamic orexin and disrupted sleep patterns, pointing to sleep loss as a possible underlying factor for cognitive deficits, a correlation that extends to attention issues observed in children who experienced early adversity.
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The widespread adoption of halide perovskites for application in thermoelectric devices, DC power generators, and lasers is hindered by their low charge carrier concentration. In particular, increasing their charge carrier concentration is considered the main challenge to serve as a promising room-temperature thermoelectric material. Efforts have been devoted to enhancing the charge carrier concentration by doping and composition engineering.

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  • Bioelectronic implants with soft mechanics and high biocompatibility show great promise for improving medical technologies by recording signals and providing treatments directly in the body.
  • Despite their potential, they still face challenges like high impedance at the bioelectronic-tissue interface, which affects their performance.
  • The introduction of OBXene, a new material with low impedance and piezoelectric properties, has led to the development of a cardiac patch that enables advanced heart mapping and pacing in animal models while being wireless and battery-free for long-term use.
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This review offers an illuminating journey through the historical evolution and modern-day applications of liquid metals, presenting a comprehensive view of their significance in diverse fields. Tracing the trajectory from mercury applications to contemporary innovations, the paper explores their pivotal role in industry and research. The analysis spans electrical switches, mechanical applications, electrodes, chemical synthesis, energy storage, thermal transport, electronics, and biomedicine.

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Metal oxide films are essential in most electronic devices, yet they are typically deposited at elevated temperatures by using slow, vacuum-based processes. We printed native oxide films over large areas at ambient conditions by moving a molten metal meniscus across a target substrate. The oxide gently separates from the metal through fluid instabilities that occur in the meniscus, leading to uniform films free of liquid residue.

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Purpose: Individuals with aphasia identify discourse-level communication (i.e., language in use) as a high priority for treatment.

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The development of wearable electronic devices for human health monitoring requires materials with high mechanical performance and sensitivity. In this study, we present a novel transparent tissue-like ionogel-based wearable sensor based on silver nanowire-reinforced ionogel nanocomposites, P(AAm--AA) ionogel-Ag NWs composite. The composite exhibits a high stretchability of 605% strain and a moderate fracture stress of about 377 kPa.

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Gallium-based liquid metals (LMs) have surface tension an order of magnitude higher than water and break up into micro-droplets when mixed with other liquids. In contrast, silicone oil readily mixes into LM foams to create oil-in-LM emulsions with oil inclusions. Previously, the LM was foamed through rapid mixing in air for an extended duration (over 2 h).

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  • The report discusses innovative infrared-modulating materials that utilize liquid metal droplets, inspired by chameleon skin, to control infrared reflection through shape changes in a silicone elastomer (Ecoflex) matrix.
  • Achievements in the system include impressive infrared camouflage capabilities with total and specular reflectances changing by approximately 44.8% and 61.2%, making it one of the most effective methods reported.
  • The system further explores programmable infrared encoding by varying liquid metal concentrations and strains, as well as incorporating temperature-sensitive alloys and multi-layer structures for improved performance.
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Glassy polymers are generally stiff and strong yet have limited extensibility. By swelling with solvent, glassy polymers can become gels that are soft and weak yet have enhanced extensibility. The marked changes in properties arise from the solvent increasing free volume between chains while weakening polymer-polymer interactions.

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Language users rely on both linguistic and conceptual processing abilities to efficiently comprehend or produce language. According to the principle of rational adaptation, the degree to which a cognitive system relies on one process vs. another can change under different conditions or disease states with the goal of optimizing behavior.

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  • High-intensity therapy is recommended for chronic poststroke aphasia, but the impact of treatment-induced fatigue on rehabilitation outcomes is not well understood.
  • The study analyzed self-rated fatigue levels of 173 participants during two types of intensive aphasia therapies, comparing a higher intensity (30 hours in 2 weeks) with a lower intensity (30 hours in 5 weeks).
  • Results showed that fatigue levels increased only slightly each day after therapy, with no evidence of accumulating fatigue over the intervention period, suggesting that intensive therapy may not significantly raise fatigue for individuals with chronic aphasia.
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  • - Gallium-based liquid metals (GaLMs) are versatile materials suitable for soft devices due to their non-toxic nature and excellent electrical and thermal conductivity compared to solids.
  • - When exposed to air or water, GaLMs develop a thin gallium oxide layer that stabilizes their surface and enhances their ability to form microstructures despite high surface tension.
  • - The review highlights how the oxide layer impacts the handling of GaLMs and their interactions with different surfaces, emphasizing the importance of interfacial properties and suggesting areas for further research.
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Metallic structures with hierarchical open pores that span several orders of magnitude are ideal candidates for various catalyst applications. However, porous metal materials prepared using alloy/dealloy methods still struggle to achieve continuous pore distribution across a broad size range. Herein, we report a printable copper (Cu)/iron (Fe) composite ink that produces a hierarchical porous Cu material with pores spanning over 4 orders of magnitude.

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Both liquid metal (LM) and metallic filler-based conductive composites are promising stretchable conductors. LM alloys exhibit intrinsically high deformability but present challenges for patterning on polymeric substrates due to high surface tension. On the other hand, conductive composites comprising metallic fillers undergo considerable decrease in electrical conductivity under mechanical deformation.

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Liquid metal (LM) particles can serve as initiators, functional fillers, and cross-linkers for hydrogels. Herein, we show that cellulose nanocrystals (CNCs) stabilize LM particles in aqueous solutions, such as those used to produce hydrogels. The CNC-coated LM particles initiate free-radical polymerization to form poly(acrylic acid) (PAA) hydrogel with exceptional properties─stretchability ∼2000%, excellent toughness ∼1.

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The fluid nature of liquid metals combined with their ability to form a solid native oxide skin enables them to be patterned in ways that would be challenging for solid metals. The present work shows a unique way of patterning liquid metals by injecting liquid metals into a mold. The mold contains a nonstick coating that enables the removal of the mold, thereby leaving just the liquid metal on the target substrate.

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Printing of stretchable conductors enables the fabrication and rapid prototyping of stretchable electronic devices. For such applications, there are often specific process and material requirements such as print resolution, maximum strain, and electrical/ionic conductivity. This review highlights common printing methods and compatible inks that produce stretchable conductors.

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Pastes and "foams" containing liquid metal (LM) as the continuous phase (liquid metal foams, LMFs) exhibit metallic properties while displaying paste or putty-like rheological behavior. These properties enable LMFs to be patterned into soft and stretchable electrical and thermal conductors through processes conducted at room temperature, such as printing. The simplest LMFs, featured in this work, are made by stirring LM in air, thereby entraining oxide-lined air "pockets" into the LM.

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Microfluidic devices began to be used to facilitate sweat and interstitial fluid (ISF) sensing in the mid-2010s. Since then, numerous prototypes involving microfluidics have been developed in different form factors for sensing biomarkers found in these fluids under , , and (on-body) settings. These devices transport and manipulate biofluids using microfluidic channels composed of silicone, polymer, paper, or fiber.

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3D or 4D printing of metal structures requires extreme conditions or a multistage process. Here, we present a protocol for the preparation of highly conductive metallic composites using liquid metal gels at ambient conditions. We describe the steps to prepare ternary gels composed of copper particles, liquid metal, and water.

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