Solid-state transformation of single precursor vanadium complex nanostructures to V₂O₅ and VO₂: catalytic activity of V₂O₅ for oxidative coupling of 2-naphthol.

A vanadium complex, [(C5H5N)2V2O3·H2O], of different morphologies has been obtained via a modified hydrothermal procedure using pyridine and VOSO4 salt as the starting material. The evolved [(C5H5N)2V2O3·H2O] nanobelts are of 50-200 nm in width and of a length up to several millimeters. At higher temperatures (600 °C), the solid [(C5H5N)2V2O3·H2O] nanostructures are converted to vanadium pentoxide (V2O5) and vanadium dioxide (VO2) when heated in air and nitrogen atmosphere, respectively.

Heterotrimetallic compounds containing Mo-M-Li [M = K, Rb and Cs] clusters: synthesis, structure, bonding, aromaticity and theoretical investigations of Li2M2 [M = K and Rb] and Cs4 rings.

A new polydentate fac-trioxo molybdenum complex, [MoO(3)L](3-) {LH(3) = nitrilotriacetic acid}, has been synthesized by the reaction of lithium molybdate with iminodiacetic acid. The trinegative complex anion coordinates the alkali metal cations, K(+), Rb(+) or Cs(+). The potassium, rubidium and cesium complexes, [Li{K(H(2)O)(2)}MoO(3)L](n) (1), [Li{Rb(H(2)O)(2)}MoO(3)L](n) (2) and [Cs{Li(H(2)O)}(2)MoO(3)L](n) (3), form heterotrimetallic coordination chains, containing planar rings of Li(2)M(2) (M = K or Rb) and Cs(4).

Synthesis and structure of a 3D porous network containing aromatic 1D chains of Li(6) rings: experimental and computational studies.

A bimetallic 3D network containing 1D chains of Li(6) unit rings has been synthesized by using a molybdenum containing metalloligand and the DFT calculations reveal that the rings are aromatic in behavior and resemble the corresponding hydrocarbon analogues.