Synthesis, Characterization and Application of Iron (III) Complex of Schiff Base Ligand as a Novel Enhancement Fluorescent Sensor for Al Ion Detection.

This study highlights the importance of developing sensitive and selective sensors for use in pharmaceutical applications for the first time. A novel iron(III)-complex, constructed from unsymmetrical tetradentate NNN'O type Schiff base ligand (E)-3-((6-aminopyridin-2-yl)imino)-1-phenyl butane-1-one (LH) and its structure of it characterized by using various spectroscopic techniques such as FT-IR, UV-Vis, elemental analysis, conductivity, magnetic susceptibility measurements and the TGA method. The correlation of all results revealed that the coordination of the (LH) with the metal ion in a molar ratio of 1:1 leads to the formation of an octahedral geometry around the metal ions.

Solvothermal synthesis of phosphorus and nitrogen doped carbon quantum dots as a fluorescent probe for iron(III).

Carbon quantum dots (CQDs) doped with phosphorus and nitrogen were prepared via a hydrothermal method starting from citric acid, urea and phosphoric acid in dimethylformamide solution. The size, morphology, surface composition, energy levels, and optical properties of the CQDs were characterized. They show both green down-conversion and up-conversion fluorescence.