Deep eutectic solvents (DES) consisting of EG-(ChCl: CHO) and TU-(ChCl: CHNS) assisted synthesized BiOCl/BiVO heterostructured catalyst studied for electrochemical uric acid (UA) sensor and tetracycline photocatalytic degradation. The chemical composition of the BiOCl/BiVO catalyst was analyzed by X-ray photoelectron spectroscopy (XPS). UV-vis spectroscopy reveals increased absorption of visible light till the near-infrared region, which results in a narrowing of band gap energy from 2.
View Article and Find Full Text PDFAntibiotics are essential medications for human and animal health, as they are used to battle urinary infections and bacterial diseases. Therefore, the rapid determination of antibiotic drugs in biological samples is necessary to address the current clinical challenge. Here, we developed a heterojunction ternary composite of BiOCl/BiVO nanosheets enriched with graphene oxide (BiOCl/BiVO@GO) for accurate and minimal-level detection of an antihistamine (promethazine hydrochloride, PMZ) in urine samples.
View Article and Find Full Text PDFHierarchical nano-/microstructured photocatalysts have drawn attention for enhanced photocatalytic performance. Deep eutectic solvents (DESs) have been used as a green sustainable media to act as both solvent and structure-inducing agent in the synthesis of hierarchical nanomaterials. In this work, the DESs-assisted synthesis of flower-structured BiOCl/BiVO (BOC/BVO) with g-C N (BOC/BVO/g-CN) ternary heterojunctions was achieved by using a simple wet-chemical method, providing good acidic and alkaline oxygen evolution reaction (OER) catalysts.
View Article and Find Full Text PDFAnion doping into the oxygen site as a new plan for tuning the physical and chemical properties of metal oxides and adjusting their catalytic behavior has been studied. Herein, we report a Cl anion-doped CuO (Cl-CuO) preparation method using deep eutectic solvents (DESs) as a green solvent, and the Cl-CuO/g-CN heterostructure was successfully prepared in various weight ratios via a simple ultrasonication and mixing method for the oxygen evolution reaction (OER) in acidic media and the photocatalytic degradation of 4-nitrophenol. Cl was doped into the CuO crystal lattice, as revealed by the XRD and XPS studies.
View Article and Find Full Text PDFHeterostructured nanomaterials can paid more significant attention in environmental safety for the detection and degradation/removal of hazardous toxic chemicals over a decay. Here, we report the preparation of hierarchically nanostructured shuriken like bismuth vanadate (BiVO) as a bifunctional catalyst for photocatalytic degradation and electrochemical detection of highly toxic hexavalent chromium (Cr(VI)) using the green deep eutectic solvent reline, which allows morphology control in one of the less energy-intensive routes. The SEM results showed a good dispersion of BiVO catalyst and the HR-TEM revealed an average particle size of ca.
View Article and Find Full Text PDFGraphene oxide-based composites have been developed as cheap and effective photocatalysts for dye degradation and water splitting applications. Herein, we report reduced graphene oxide (rGO)/Ag/Fe-doped TiO that has been successfully prepared using a simple process. The resulting composites were characterized by a wide range of physicochemical techniques.
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