Publications by authors named "Dharmraj Prajapati"
Article Synopsis
- - The research discusses the creation of a low-symmetry metallo-supramolecular barrel (UNMB) using an unsymmetrical tetratopic ligand and a protected Pd(ii) metal acceptor, deviating from typical symmetric assemblies.
- - Different orientational isomers of the barrel were predicted, with experimental results indicating that the HHTT isomer was formed, verified through X-ray diffraction and H NMR analysis.
- - UNMB has large openings and a hydrophobic interior, making it effective at encapsulating larger guests like fullerenes, with a preference for C₆₀ over C₇₀, enabling potential applications in separation processes.
Quinones (QN) are one of the main components of diesel exhaust particulates that have significant detrimental effects on human health. Their extraction and purification have been challenging tasks because these atmospheric particulates exist as complex matrices consisting of inorganic and organic compounds. In this report, we introduce a new water soluble PdL molecular architecture (MT) with an unusual tweezer-shaped structure obtained by self-assembly of a newly designed phenothiazine-based tetra-imidazole donor (L) with the acceptor -[(tmeda)Pd(NO)] (M) [ tmeda = ,,','-tetramethylethane-1,2-diamine].
View Article and Find Full Text PDFPhenanthrene is a high-value raw material in chemical industries. Separation of phenanthrene from isomeric anthracene continues to be a big challenge in the industry due to their very similar physical properties. Herein, we report the self-assembly of a water-soluble molecular bowl () from a phenothiazine-based unsymmetrical terapyridyl ligand () and a -blocked 90° Pd(II) acceptor.
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