Publications by authors named "Devi Prasad Adiyeri Saseendran"
We report on the synthesis and spectroscopic evidence for a sequence of structural transformations of a new defect-cubane type copper complex, [Cu(pyalk)(OAc)](ClO)(HNEt), which acts as a pre-catalyst for water oxidation. and post-catalytic studies showed that the tetrameric complex undergoes a structural transformation into dimeric and monomeric species, induced by water molecules and carbonate anions, respectively. Further, the observed electrocatalytic water oxidation activity has been confirmed to arise from -generated Cu(II) oxidic nanostructures at the electrode interface.
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- The oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) are essential for energy conversion and storage, but improving their efficiency is hindered by slow reaction rates and complex catalyst-electrolyte interactions.
- Recent advancements in characterization techniques allow for better understanding of these catalysts' mechanisms, specifically focusing on transition metals in basic conditions.
- The review highlights key aspects such as determining active species, identifying active sites, and monitoring intermediates, while also discussing strategies for designing more effective catalysts and addressing ongoing challenges in the field.