Resilient and Reversible Phosphotungstic Acid Passivated Zinc Anode.

Aqueous zinc ion batteries (ZIBs) present a compelling solution for grid-scale energy storage, which is crucial for integrating renewable energy resources into the electric infrastructure. The cycling stability of ZIBs hinges on the electrochemical reversibility of the zinc anode, which is often compromised by corrosion and dendritic zinc deposition. Here, we present a straightforward surface passivation strategy that significantly enhances the cycling stability of zinc anodes.