Environ Sci Process Impacts
November 2024
Ice nucleation processes in the earth's atmosphere are critical for cloud formation, radiation, precipitation, and climate change. We investigated the physicochemical properties and ice nucleation potential of selected viral aerosols, including their RNA and proteins, using advanced techniques such as scanning-transmission electron microscopy (S/TEM), small angle X-ray scattering (SAXS), particle analyzers, and a peltier chamber. The experiments revealed that RNA particles obtained from MS2 bacteriophage had a mean freezing point of -13.
View Article and Find Full Text PDFLittle is known about the role of starchy food on climate change processes like ice nucleation. Here, we investigate the ice nucleation efficiency (INE) of eight different starchy food materials, namely, corn (CO), potato (PO), barley (BA), brown rice (BR), white rice (WR), oats (OA), wheat (WH), and sweet potato (SP), in immersion freezing mode under mixed-phase cloud conditions. Notably, among all these food materials, PO and BA exhibit the highest ice nucleation efficiency with ice nucleation temperatures as high as -4.
View Article and Find Full Text PDFFor the first time, we present a much-needed technology for the in situ and real-time detection of nanoplastics in aquatic systems. We show an artificial intelligence-assisted nanodigital in-line holographic microscopy (AI-assisted nano-DIHM) that automatically classifies nano- and microplastics simultaneously from nonplastic particles within milliseconds in stationary and dynamic natural waters, without sample preparation. AI-assisted nano-DIHM identifies 2 and 1% of waterborne particles as nano/microplastics in Lake Ontario and the Saint Lawrence River, respectively.
View Article and Find Full Text PDFNumerous anthropogenic and natural particle contaminants exist in diverse aquatic systems, with widely unknown environmental fates. We coupled a flow tube with a digital in-line holographic microscopy (nano-DIHM) technique for aquatic matrices, for real-time analysis of particle size, shape, and phase. Nano-DIHM enables 4D tracking of particles in water and their transformations in three-dimensional space.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
August 2022
Airports are identified hotspots for air pollution, notably for fine particles (PM) that are pivotal in aerosol-cloud interaction processes of climate change and human health. We herein studied the field observation and statistical analysis of 10-year data of PM and selected emitted co-pollutants (CO, NO, and O), in the vicinity of three major Canadian airports, with moderate to cold climates. The decadal data analysis indicated that in colder climate airports, pollutants like PM and CO accumulate disproportionally to their emissions in fall and winter, in comparison to airports in milder climates.
View Article and Find Full Text PDFIn situ and real-time characterization of aerosols is vital to several fundamental and applied research domains including atmospheric chemistry, air quality monitoring, or climate change studies. To date, digital holographic microscopy is commonly used to characterize dynamic nanosized particles, but optical traps are required. In this study, a novel integrated digital in-line holographic microscope coupled with a flow tube (Nano-DIHM) is demonstrated to characterize particle phase, shape, morphology, 4D dynamic trajectories, and 3D dimensions of airborne particles ranging from the nanoscale to the microscale.
View Article and Find Full Text PDFBull World Health Organ
February 2021
Objective: To compare ambient air quality standards for the mass concentration of aerosol particles smaller than approximately 2.5 μm (PM) and exposure to these particles in national and regional jurisdictions worldwide.
Methods: We did a review of government documents and literature on air quality standards.
Airborne particles, specifically nanoparticles, are identified health hazards and a key research domain in air pollution and climate change. We performed a systematic airport study to characterize real-time size and number density distribution, chemical composition and morphology of the aerosols (∼10 nm-10 μm) using complementary cutting-edge and novel techniques, namely optical aerosol analyzers, triple quad ICP-MS/MS and high-resolution STEM imaging. The total number density of aerosols, predominantly composed of nanoparticles, reached a maximum of 2 × 10 cm and is higher than reported values from any other international airport.
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