Spectrochim Acta A Mol Biomol Spectrosc
January 2020
Herein, colloidal CdS QDs have been synthesized by using cysteine as a stabilizing agent. The interaction between the CdS QDs and selenious acid was monitored by using UV-visible, fluorescence and Fourier transform infrared (FTIR) spectroscopy. The onset of absorption of the CdS QDs (430 nm) was progressively red-shifted upon increase in the concentration of selenious acid at pH 10.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
May 2019
The purpose of the present research was to design a method for the colorimetric determination of cysteamine. We have employed cysteine-stabilized silver nanoparticles (AgNPs) as a probe. The addition of cysteamine resulted in the quenching of the 400 nm surface plasmon resonance (SPR) band of the AgNPs.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2018
The purpose of the present work was to develop a method for the sensing of thioacetamide by using spectroscopic techniques. Thioacetamide is a carcinogen and it is important to detect its presence in food-stuffs. Semiconductor quantum dots are frequently employed as sensing probes since their absorption and fluorescence properties are highly sensitive to the interaction with substrates present in the solution.
View Article and Find Full Text PDFWe have used fluorescent ZnS nanoparticles as a probe for the determination of adenine. A typical 2 × 10(-7) M concentration of adenine quenches 39.3% of the ZnS fluorescence.
View Article and Find Full Text PDFWe present a novel method for the selective detection of cysteine, a sulfur-containing amino acid, which plays a crucial role in many important biological functions such as protein folding. Surface-modified colloidal CdS nanoparticles have been used as a fluorescent probe to selectively detect cysteine in the presence of other amino acids in the micromolar concentration range. Cysteine quenches the emission of CdS in the 0.
View Article and Find Full Text PDFThe photophysics of Cd(OH)(2)-coated Q-CdS in the presence of guanine and related compounds has been examined. Guanine and adenine quench the bandgap emission and reduce the emission lifetime of these particles. Approximately 50% of the bandgap fluorescence is quenched by a low [guanine] (2x10(-5) mol dm(-3)).
View Article and Find Full Text PDF