Publications by authors named "Devaraj Nataraj"

Article Synopsis
  • Carbon quantum dots (CQDs) derived from Walnut Shell biomass have been studied as effective fluorescent sensors for detecting Acebrophylline (AB), a medication for respiratory diseases.
  • The CQDs exhibit high selectivity and sensitivity towards AB, with a detection limit of 0.142 nM and strong performance in human urine samples, achieving recovery rates between 81 to 123%.
  • The study also analyzed structural changes in CQDs after sensing AB and explored the effects of various factors on detection, emphasizing the method's eco-friendly and cost-effective potential for healthcare applications.
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Nonclassical crystallization represents an innovative pathway that utilizes nanoparticles, enabling the generation of single crystals, going beyond a classical mechanism dependent on atoms, ions, or molecules. Our investigation has revealed hierarchical structures emerging via the aggregation and fusion of primary silicon quantum dots (SiQDs). In contrast to the classical ion-by-ion crystallization process, the primary SiQDs initially undergo aggregation, followed by fusion and their subsequent crystallization, leading to the ultrafast crystal growth of sodium hexafluorosilicate (SHFS) microrods with diverse morphologies.

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The formation of plasmon-exciton (plexciton) polariton is a direct consequence of strong light-matter interaction, and it happens in a semiconductor-metal hybrid system. Here the formation of plasmon-exciton polaritons was observed from an AgTe/CdTe Quantum Dot (QD) solid system in the strong coupling regime. The strong coupling was achieved by increasing the oscillator strength of the excitons by forming coupled QD solids.

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Correction for 'Induced UV photon sensing properties in narrow bandgap CdTe quantum dots through controlling hot electron dynamics' by Thankappan Thrupthika , , 2023, https://doi.org/10.1039/d3cp02424e.

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Mn-doped CdTe (Mn-CdTe) quantum dot (QD) as well as quantum dot solid (QD solid) nanostructures are formed and the established structures are confirmed through HR-TEM analysis. The dynamics of charge carriers in both doped & undoped QD and QD solid structures were investigated by transient absorption (TA) spectroscopy. A slow band edge bleach recovery is obtained for Mn-doped CdTe QD and CdTe QD solid systems at room temperature.

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The existence and usage of nano-sized palladium (nano-Pd) as catalytic promoters among industries and researchers have been laid a way to explore the release of nano-Pd particles into the aquatic environment, bio-accumulating in living organisms. However, the data on fate and toxicity in response to nano-Pd on aquatic organisms are very limited. Herein, we report the concentration-specific toxicity of nano-Pd in zebrafish (Danio rerio).

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Article Synopsis
  • Blue emission from Oleylamine-Acetone clusters forms at room temperature through aging-induced hydrogen bonding, producing flower-like aggregates that emit red light due to exciton delocalization.
  • The aging process leads to imine bond formation between Oleylamine and Acetone, and the paper details the experimental setup and mechanisms behind these molecular interactions.
  • The research also applies this aging method to InS quantum dot systems, demonstrating improved charge transport in photoconductive devices by detaching Oleylamine from the QD surface, ultimately achieving high photocurrent values.
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Trace determination of radioactive waste, especially Ce, by electrochemical methods has rarely been attempted. Ce is (i) a fluorescence quencher, (ii) an antiferromagnet, and (iii) a superconductor, and it has been incorporated into fast scintillators, LED phosphors, and fluorescent lamps. Although Ce has been utilized in many industries due to its specific properties, it causes severe health problems to human beings because of its toxicity.

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Graphene-nanostructured systems, such as graphene quantum dots (GQDs), are well known for their interesting light-emitting characteristics and are being applied to a variety of luminescence-based applications. The emission properties of GQDs are complex. Therefore, understanding the science of the photophysics of coupled quantum systems (like quantum clusters) is still challenging.

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Detection of visible blind UV radiation is not only interesting but also of technologically important. Herein, we demonstrate the efficient detection of UV radiation by using cluster like ZnS quantum dot solid nanostructures prepared by simple reflux condensation technique. The short-chain ligand 3-mercaptopropionic acid (MPA) involved in the synthesis lead to the cluster like formation of ZnS quantum dots into solids upon prolonged synthesis conditions.

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Article Synopsis
  • The detection of highly toxic chemicals, like phosgene, is crucial due to health risks and security threats.
  • A study focused on developing a sensor using 1,8-diaminonaphthalene-functionalized graphene quantum dots (DAN-GQDs) to detect phosgene in water.
  • The DAN-GQDs demonstrated high selectivity and sensitivity, with a limit of detection of 2.26 ppb, making them a promising tool for monitoring this dangerous chemical in aqueous solutions.
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The control of filariasis vectors has been enhanced in several areas, but there are main challenges, including increasing resistance to insecticides and lack of cheap and eco-friendly products. The toxicity of iron (Fe) and iron oxide (FeO) nanoparticles has been scarcely investigated yet. We studied the larvicidal and pupicidal activity of Fe and FeO nanoparticles against Culex quinquefasciatus.

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Graphene has been studied intensively in opto-electronics, and its transport properties are well established. However, efforts to induce intrinsic optical properties are still in progress. Herein, we report the production of micron-sized sheets by interconnecting graphene quantum dots (GQDs), which are termed 'GQD solid sheets', with intrinsic absorption and emission properties.

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The present study focus on optical sensing of breast cancer antigen 15.3 (CA 15.3) using cadmium sulphide quantum dot (CdS-QD) in saline and serum samples spiked with antigen.

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A main challenge in parasitology is the development of reliable tools to prevent or treat mosquito-borne diseases. We investigated the toxicity of magnetic nanoparticles (MNP) produced by Magnetospirillum gryphiswaldense (strain MSR-1) on chloroquine-resistant (CQ-r) and sensitive (CQ-s) Plasmodium falciparum, dengue virus (DEN-2), and two of their main vectors, Anopheles stephensi and Aedes aegypti, respectively. MNP were studied by Fourier-transform infrared spectroscopy and transmission electron microscopy.

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Mosquito-borne diseases represent a deadly threat for millions of people worldwide. The Culex genus, with special reference to Culex quinquefasciatus, comprises the most common vectors of filariasis across urban and semi-urban areas of Asia. In recent years, important efforts have been conducted to propose green-synthesized nanoparticles as a valuable alternative to synthetic insecticides.

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