Publications by authors named "Deoukchen Ghim"

Article Synopsis
  • Heterogeneous solid nucleation on membranes, driven by favorable thermodynamics and kinetics, leads to early-stage mineral scaling, specifically with iron (hydr)oxide.
  • The study used advanced techniques like grazing incidence small-angle X-ray scattering and atomic force microscopy to analyze how iron (hydr)oxide interacts with various membrane surface functional groups (OH, COOH, F).
  • Results showed that hydrophobic F-modified surfaces significantly reduced nucleation rates compared to hydrophilic surfaces like OH and COOH, with OH surfaces having faster nucleation due to higher functional group density and a lower energy barrier for nucleation.
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All solid materials are created via nucleation. In this evolutionary process, nuclei form in solution or at interfaces, expand by monomeric growth and oriented attachment, and undergo phase transformation. Nucleation determines the location and size of nuclei, whereas growth controls the size, shape, and aggregation of newly formed nanoparticles.

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The distinctive optical and electronic properties of two-dimensional (2D) molybdenum disulfide (MoS) make it a promising photocatalyst and photothermal agent in aqueous applications. In terms of environmental stability, MoS has been considered insoluble, but 2D MoS nanosheets can be susceptible to dissolution, owing to their large surface areas and highly accessible reactive sites, including defects at the basal plane and edge sites. Under light illumination, the dissolution of 2D MoS nanosheets can be further accelerated by their photochemical reactivity.

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Herein, the recent advances in realizing highly efficient cellulose-based solar evaporators for alleviating the global water crisis are summarized. Fresh water scarcity is one of the most threatening issues for sustainable development. Solar steam generation, which harnesses the abundant sunlight, has been recognized as a sustainable approach to harvest fresh water.

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In meeting the increasing need for clean water in both developing and developed countries and in rural and urban communities, photothermal membrane water treatment technologies provide outstanding advantages: For developing countries and rural communities, by utilizing sunlight, photothermal membrane water treatment provides inexpensive, convenient, modular, decentralized, and accessible ways to clean water, which can reduce the consumption of conventional energy (e.g., electricity, natural gas) and the cost of clean water production.

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Biofouling poses one of the most serious challenges to membrane technologies by severely decreasing water flux and driving up operational costs. Here, we introduce a novel anti-biofouling ultrafiltration membrane based on reduced graphene oxide (RGO) and bacterial nanocellulose (BNC), which incoporates GO flakes into BNC in situ during its growth. In contrast to previously reported GO-based membranes for water treatment, the RGO/BNC membrane exhibited excellent aqueous stability under environmentally relevant pH conditions, vigorous mechanical agitation/sonication, and even high pressure.

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Large quantities of highly toxic organic dyes in industrial wastewater is a persistent challenge in wastewater treatment processes. Here, for highly efficient wastewater treatment, a novel membrane based on bacterial nanocellulose (BNC) loaded with graphene oxide (GO) and palladium (Pd) nanoparticles is demonstrated. This Pd/GO/BNC membrane is realized through the in situ incorporation of GO flakes into BNC matrix during its growth followed by the in situ formation of palladium nanoparticles.

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