Incommensurate Antiferromagnetic Order in Weakly Frustrated Two-Dimensional van der Waals Insulator CrPSe.

Although magnetic order is suppressed by a strong frustration, it appears in complex forms such as a cycloid or spin density wave in weakly frustrated systems. Herein, we report a weakly magnetically frustrated two-dimensional (2D) van der Waals material CrPSe. Polycrystalline CrPSe was synthesized at an optimized temperature of 700 °C to avoid the formation of any secondary phases (e.

Structural Features of the Fragments from Cast Iron Cauldrons of the Medieval Golden Horde: Neutron Tomography Data.

The spatial arrangement of the internal pores inside several fragments of ancient cast iron cauldrons related to the medieval Golden Horde period was studied using the neutron tomography method. The high neutron penetration into a cast iron material provides sufficient data for detailed analysis of the three-dimensional imaging data. The size, elongation, and orientation distributions of the observed internal pores were obtained.

High Pressure-Driven Magnetic Disorder and Structural Transformation in Fe GeTe : Emergence of a Magnetic Quantum Critical Point.

Among the recently discovered 2D intrinsic van der Waals (vdW) magnets, Fe GeTe (FGT) has emerged as a strong candidate for spintronics applications, due to its high Curie temperature (130 - 220 K) and magnetic tunability in response to external stimuli (electrical field, light, strain). Theory predicts that the magnetism of FGT can be significantly modulated by an external strain. However, experimental evidence is needed to validate this prediction and understand the underlying mechanism of strain-mediated vdW magnetism in this system.

Structural, Magnetic and Vibrational Properties of Van Der Waals Ferromagnet CrBr at High Pressure.

The crystal and magnetic structures of van der Waals layered ferromagnet CrBr3 were studied using X-ray powder diffraction and neutron powder diffraction at pressures up to 23 GPa at ambient temperature and up to 2.8 GPa in the temperature range 6-300 K, respectively. The vibration spectra of CrBr3 were studied using Raman spectroscopy at pressures up to 23 GPa at ambient temperature.

Crystallization Pathways and Evolution of Morphologies and Structural Defects of α-MnO under Air Annealing.

Manganese dioxide nanomaterials have wide applications in many areas from catalysis and Li-ion batteries to gas sensing. Understanding the crystallization pathways, morphologies, and formation of defects in their structure is particularly important but still a challenging issue. Herein, we employed an arsenal of X-ray diffraction (XRD), scanning electron microscopy (SEM), neutron diffraction, positron annihilation spectroscopies, and calculations to investigate the evolution of the morphology and structure of α-MnO nanomaterials prepared via reduction of KMnO solution with CHOH prior to being annealed in air at 200-600 °C.

Pore Segmentation Techniques for Low-Resolution Data: Application to the Neutron Tomography Data of Cement Materials.

The development of neutron imaging facilities provides a growing range of applications in different research fields. The significance of the obtained structural information, among others, depends on the reliability of phase segmentation. We focused on the problem of pore segmentation in low-resolution images and tomography data, taking into consideration possible image corruption in the neutron tomography experiment.

Neutron Tomography Studies of Two Lamprophyre Dike Samples: 3D Data Analysis for the Characterization of Rock Fabric.

The rock fabric of two lamprophyre dike samples from the Koy-Tash granitoid intrusion (Koy-Tash, Jizzakh region, Uzbekistan) has been studied, using the neutron tomography method. We have performed virtual segmentation of the reconstructed 3D model of the tabular igneous intrusion and the corresponding determination of dike margins orientation. Spatial distributions of inclusions in the dike volume, as well as further analysis of size distributions and shape orientations of inclusions, have been obtained.

Phase Composition and Its Spatial Distribution in Antique Copper Coins: Neutron Tomography and Diffraction Studies.

The chemical and elementary composition, internal arrangement, and spatial distribution of the components of ancient Greek copper coins were studied using XRF analysis, neutron diffraction and neutron tomography methods. The studied coins are interesting from a historical and cultural point of view, as they are "Charon's obol's". These coins were discovered at the location of an ancient Greek settlement during archaeological excavations on the "Volna-1" necropolis in Krasnodar Region, Russian Federation.

The Reconstruction of a Bronze Battle Axe and Comparison of Inflicted Damage Injuries Using Neutron Tomography, Manufacturing Modeling, and X-ray Microtomography Data.

A massive bronze battle axe from the Abashevo archaeological culture was studied using neutron tomography and manufacturing modeling from production molds. Detailed structural data were acquired to simulate and model possible injuries and wounds caused by this battle axe. We report the results of neutron tomography experiments on the bronze battle axe, as well as manufactured plastic and virtual models of the traumas obtained at different strike angles from this axe.

Structural and Magnetic Transitions in CaCoVO Perovskite at Extreme Conditions.

We investigated the structural, vibrational, magnetic, and electronic properties of the recently synthesized CaCoVO double perovskite with the high-spin (HS) Co ions in a square-planar oxygen coordination at extreme conditions of high pressures and low temperatures. The single-crystal X-ray diffraction and Raman spectroscopy studies up to 60 GPa showed a conservation of its cubic crystal structure but indicated a crossover near 30 GPa. Above 30 GPa, we observed both an abnormally high "compressibility" of the Co-O bonds in the square-planar oxygen coordination and a huge anisotropic displacement of HS-Co ions in the direction perpendicular to the oxygen planes.

Charge-ordering transition in iron oxide Fe4O5 involving competing dimer and trimer formation.

Phase transitions that occur in materials, driven, for instance, by changes in temperature or pressure, can dramatically change the materials' properties. Discovering new types of transitions and understanding their mechanisms is important not only from a fundamental perspective, but also for practical applications. Here we investigate a recently discovered Fe4O5 that adopts an orthorhombic CaFe3O5-type crystal structure that features linear chains of Fe ions.

The Pressure-Induced Polymorphic Transformations in Fluconazole.

The structural properties and Raman spectra of fluconazole have been studied by means of X-ray diffraction and Raman spectroscopy at pressures up to 2.5 and 5.5 GPa, respectively.

The polymorphic phase transformations in the chlorpropamide under pressure.

The crystal structure and vibrational spectra of the chlorpropamide have been studied by means of the X-ray diffraction and Raman spectroscopy at pressures up to 24.6 and 4.4 GPa, respectively.