Publications by authors named "Deepalekshmi Ponnamma"

Electromagnetic induction (EMI) shielding has become essential across various industries to counteract the detrimental impact of EMI on electronic devices and delicate machinery. Traditional EMI shielding materials, predominantly composed of metals and metal alloys, raise environmental concerns due to their non-biodegradability and energy-intensive manufacturing processes. Consequently, demand for environmentally friendly materials for EMI shielding applications is rising.

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Carbon dots (CDs) have emerged as a versatile and promising carbon-based nanomaterial with exceptional optical properties, including tunable emission wavelengths, high quantum yield, and photostability. CDs are appropriate for various applications with many benefits, such as biocompatibility, low toxicity, and simplicity of surface modification. Thanks to their tunable optical properties and great sensitivity, CDs have been used in sensing as fluorescent probes for detecting pH, heavy metal ions, and other analytes.

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In our pursuit of a flexible energy storage solution, we have developed biocompatible (bc)-NG/PVA composite polymers by combining neem tree gum (NG) with polyvinyl alcohol (PVA). This innovative bio-inspired approach harnesses NG's unique properties for both the bio-electrolyte and bio-electrode components. The resulting bc-NG/PVA composites exhibit superior dielectric strength and versatility, surpassing traditional inorganic ceramic dielectrics in advanced electronics and pulsed power systems.

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Article Synopsis
  • The breath figure imprinting technique allows for the creation of micro-patterned membranes with specific pore sizes by using fast polymer evaporation in humid conditions, although understanding the complex dynamics of this process is still a challenge.
  • This study focuses on using porous membranes made from polylactic acid (PLA) combined with two additives: polyvinylidene fluoride (PVDF) and zinc oxide nanoparticles (ZnO NPs), chosen for their distinct properties and potential synergistic effects to improve the structure and functionality of the membranes.
  • The research investigates how these additives affect the morphology and chemical properties of the PLA membranes, ultimately aiming to enhance our understanding of their assembly and to explore their potential applications across
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Article Synopsis
  • * The article reviews fabrication techniques for NC-2D membranes and summarizes their physico-chemical properties, which influence their performance in water treatment.
  • * Key aspects discussed include how these membranes perform in terms of permeability, fouling resistance, and their long-term stability, with suggestions for future research to enhance their practical use in addressing water pollution challenges.
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Self-powered devices based on piezoelectric nanogenerators (PENGs) are becoming crucial in the upcoming smart societies as they can integrate multifunctional applications, especially sensing, energy storage, In this work, we explore the piezoelectric voltage generation happening in polyvinylidene fluoride (PVDF) nanocomposites developed by phase separation. The simple method adopted for the nanocomposite synthesis rules out the high voltage required for the normal electrospun PENGs and adds to their cost-effectiveness. Zinc-doped iron oxide (Zn-FeO) nanomaterials influence the piezoelectric properties by enhancing the crystallinity and structural properties of the polymer.

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Society 5.0 establishes innovations and innovativeness as the basic platforms for accelerating the development of solution-based strategies for the sustainability problems every society is facing. It features an interactive cycle operating at a society-wide level through which data are collected, analyzed and transformed into applicable technology for the real world.

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Simplified and flexible fabrication methods, high output performance, and extreme flexibility of polymer-based nanocomposites represent versatile designs in self-powering devices for wearable electronics, sensors, and smart societies. Examples include polyvinylidene fluoride and its copolymers-based piezoelectric nanogenerators, green and recyclable triboelectric nanogenerators, etc. Advanced functionalities, multi-functional properties, and the extensive lifetime required for nanogenerators inspire researchers to focus on structural modifications of the polymeric materials, to fully exploit their performances.

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Global warming due to the high concentration of anthropogenic CO in the atmosphere is considered one of the world's leading challenges in the 21 century as it leads to severe consequences such as climate change, extreme weather events, ocean warming, sea-level rise, declining Arctic sea ice, and the acidification of oceans. This encouraged advancing technologies that sequester carbon dioxide from the atmosphere or capture those emitted before entering the carbon cycle. Recently, CO capture, utilizing porous materials was established as a very favorable route, which has drawn extreme interest from scientists and engineers due to their advantages over the absorption approach.

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Despite the photocatalytic organic pollutant degradation using ZnO started in 1910-1911, many challenges are still ahead, and several critical issues have to be addressed. Large band gap, and short life-time of photogenerated electrons and holes are critical issues negatively affect the photocatalytic activity of ZnO. Various approaches have been introduced to overcome these issues including intrinsic doping, extrinsic doping, and heterostructure.

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Melamine (MA) and polyurethane (PU) foams, including both commercial sponges for daily use as well as newly synthesized foams are known for their high sorption ability of both polar and unipolar liquids. From this reason, commercial sponges are widely used for cleaning as they absorb a large amount of water, oil as well as their mixtures. These sponges do not preferentially absorb any of those components due to their balanced wettability.

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Over the last few decades, various volatile organic compounds (VOCs) have been widely used in the processing of building materials and this practice adversely affected the environment i.e. both indoor and outdoor air quality.

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Hydrophobic microporous polystyrene (PS) fibers are fabricated by a solvent-induced phase-separation-assisted electrospinning method. Zinc oxide (ZnO) and silver-doped zinc oxide (Ag-ZnO) nanomaterials with variable morphologies are added to the PS fibers, to investigate the influence of multifunctional nanofiller addition on the porosity and consequent oil-adsorbing properties for different oil types. The doping of silver as well as the uniformity in particle distribution are confirmed by scanning electron microscopy and the energy-dispersive spectral analyses.

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Tissue engineering (TE) and regenerative medicine integrate information and technology from various fields to restore/replace tissues and damaged organs for medical treatments. To achieve this, scaffolds act as delivery vectors or as cellular systems for drugs and cells; thereby, cellular material is able to colonize host cells sufficiently to meet up the requirements of regeneration and repair. This process is multi-stage and requires the development of various components to create the desired neo-tissue or organ.

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Metallic implants have dominated the biomedical implant industries for the past century for load-bearing applications, while the polymeric implants have shown great promise for tissue engineering applications. The surface properties of such implants are critical as the interaction of implant surfaces, and the body tissues may lead to unfavourable reactions. Desired implant properties are biocompatibility, corrosion resistance, and antibacterial activity.

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Non-enzymatic sensing has been in the research limelight, and most sensors based on nanomaterials are designed to detect single analytes. The simultaneous detection of analytes that together exist in biological organisms necessitates the development of effective and efficient non-enzymatic electrodes in sensing. In this regard, the development of sensing elements for detecting glucose and hydrogen peroxide (HO) is significant.

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Flexible piezoelectric nanogenerators (PENG) are widely applied to harvest sustainable energy from multiple energy sources. The rational and simple design of PENG have great potential in soft electronics. Here we design a highly flexible PENG using the polyvinylidene fluoride (PVDF) and its copolymer, polyvinylidene hexafluoropropylene (PVDF-HFP) with two nanoarchitectures of semiconducting metal oxides, TiO and ZnO.

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The separation of oil from water and filtration of aqueous solutions and dispersions are critical issues in the processing of waste and contaminated water treatment. Membrane-based technology has been proven as an effective method for the separation of oil from water. In this research, novel vertical nanopores membrane, via oriented cylindrical block copolymer (BCP) films, suitable for oil/water filtration has been designed, fabricated and tested.

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The present study aims to synthesize biocompatible and bioactive lanthanum (La)/strontium (Sr) dual ion doped hydroxyapatite (HA) nanomaterials by sol-gel method. The discrete substitution of La and Sr in pure HA enhances the osteoconductivity. The co-substitution of various La concentrations (0.

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In this work, stable hydrophobic nanocomposites are made from electrospun fibers of polystyrene (PS) containing a hybrid filler combination of (i) hexagonal boron nitride (hBN) and (ii) cobalt oxide (CoO) nanomaterials. Good synergistic interaction is observed between the nanomaterials, since the growth of CoO was carried out in presence of white graphene nanosheets. Filler synergy modifies the PS surfaces, by enhancing the filler-polymer interfacial interactions and provides good tensile strength.

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Article Synopsis
  • * ZnO nanostructures produced using this technique show enhanced photocatalytic activity for breaking down methyl orange compared to those made through traditional methods, due to factors like smaller particle size and surface defects.
  • * The method is also effective in creating porous FeO nanostructures and few-layer BiO nanosheets, with BiO/ZnO heterostructures demonstrating superior photocatalytic performance compared to those synthesized by conventional approaches.
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Development of flexible piezoelectric nanogenerator (PENG) is a real challenge for the next-generation energy-harvesting applications. In this paper, we report highly flexible PENGs based on poly(vinylidene fluoride) (PVDF)/2 wt % Ce-FeO and PVDF/2 wt % Ce-CoO nanocomposite fibers. The incorporation of magnetic Ce-FeO and Ce-CoO greatly affects the structural properties of PVDF nanofibers, especially the polymeric β and γ phases.

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Limited light absorption, inefficient electron-hole separation, and unsuitable positions of conduction band bottom and/or valence band top are three major critical issues associated with high-efficiency photocatalytic water treatment. An attempt has been carried out here to address these issues through the synthesis of direct -scheme CsO-BiO-ZnO heterostructures via a facile, fast, and economic method: solution combustions synthesis. The photocatalytic performances are examined by the 4-chlorophenol degradation test under simulated sunlight irradiation.

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Carbon-based materials are outstanding candidates for oil spill clean-ups due to their superhydrophobicity, high surface area, chemical inertness, low density, recyclability, and selectivity. The current work deals with the fabrication of membrane oil absorbents based on carbon nanotube (CNT) reinforced polystyrene (PS) nanocomposites by electrospinning technique. The spun membranes are also irradiated with the gamma radiation to induce enough crosslinks and thus good polymer-filler interactions.

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