Publications by authors named "Deepa Sriramulu"

Membrane capacitive deionization (MCDI) is an effective process to remove salt ions from brackish water. In this work, a systematic investigation was carried out to study the effects of applied potential and salt concentration on salt adsorption capacity (SAC), charge efficiency () and energy consumption in an MCDI system using biowaste derived carbon as electrodes. We studied the comparative MCDI performance of derived carbon as electrodes before and after activation.

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In recent years, capacitive deionization (CDI) has emerged as an energy efficient and cost-effective technology for the desalination of brackish water. However, high energy consumption and poor desalting efficiency at high salinity levels have hampered the application of CDI for seawater (∼35 000 mg L-1). A novel method of CDI termed hybrid capacitive deionization (HCDI) employs the use of a faradaic electrode paired with a capacitive electrode.

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In this study, we introduced an efficient hybrid capacitive deionization (HCDI) system for removal of NaCl from brackish water, in which Prussian blue nanocubes embedded in a highly conductive reduced graphene oxide aerogel have been used as a binderfree intercalation anode to remove Na ions. The combination of redox-active nanocubes and the three-dimensional porous graphene network yielded a high salt removal capacity of 130 mg g at the current density of 100 mA g. Moreover, energy recovery and energy consumption upon different desorption voltages of the HCDI system were investigated and the result showed a notably low energy consumption of 0.

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Optically active silica nanoparticles are interesting owing to high stability and easy accessibility. Unlike previous reports on dye loaded silica particles, here we address an important question on how optical properties are dependent on the aggregation-induced segregation of perylene molecules inside and outside the silica nanoparticles. Three differentially functionalized fluorescent perylene - silica hybrid nanoparticles are prepared from appropriate ratios of perylene derivatives and tetraethyl orthosilicate (TEOS) and investigated the structure property correlation (P-ST, P-NP and P-SF).

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Multifunctional coatings offer many advantages towards protecting various surfaces. Here we apply aggregation induced segregation of perylene diimide (PDI) to control the surface morphology and properties of silica nanoparticles. Differentially functionalized PDI was incorporated on the surface of silica nanoparticles through Si-O-Si bonds.

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Recently photocatalytic treatment of municipal reverse osmosis concentrate (ROC) has drawn increasing attention due to its relatively high efficiency and low cost. However, photocatalytic reactions by commercially available TiO₂ are not able to degrade fluorosurfactants in the ROC sample due to the absence of photoreactive groups in these compounds. Here we investigated adsorption and coagulation methods and their efficiencies in removing fluorosurfactants.

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