This paper investigates the effect of Chinese outward foreign direct investment (FDI) on youth unemployment in sub-Saharan Africa (SSA) by using a modified labour demand model to identify the investment sources that are helpful for reducing youth unemployment in the region. The model is applied to a panel of 42 countries for the period 2003-2021 using random-effect, and generalized method of moment (GMM) estimators for robustness check. Our results suggest that Chinese FDI has direct short-term reducing effect on youth unemployment in SSA.
View Article and Find Full Text PDFThis study presents a halide exchange mediated cation exchange reaction to co-dope d- and f-block elements in CsPbX NPs at room temperature. Addition of MnCl and YbCl to CsPbBr NPs induces ion exchange reactions generating the corresponding CsPbBr/MnClYbCl NPs. In addition to the perovskite emission, the NPs display sensitized Mn and Yb emissions in concert spanning the UV, visible, and NIR spectral region.
View Article and Find Full Text PDFChiral metal halide perovskites have garnered substantial interest because of their promising properties for application in optoelectronics and spintronics. Understanding the mechanism of chiral imprinting is paramount for optimizing their utility. To elucidate the nature of the underlying chiral imprinting mechanism, we investigated how the circular dichroism (CD) intensity varies with nanoparticle size for quantum confined sizes of colloidal CsPbBr perovskite nanoparticles (NPs) capped by chiral β-methylphenethylammonium bromide ligands.
View Article and Find Full Text PDFThis study investigates granger causal linkages among six Asian emerging stock markets and the US market over the period 2002-2020, taking into account several crisis periods. The pairwise Granger causality tests for investigating the short-run causality show significant bi- and uni-directional causal relationships in those markets and evidence that they have become more internationally integrated after every crisis period. An exception is Bangladesh with almost no significant short-term causal linkages with other markets.
View Article and Find Full Text PDFIntroduction: Chronic liver disease (CLD) represents different liver disorders of varying severity and etiology in which hepatic inflammation and fibrosis continue at least for 6 months. Portal hypertension is one of the important complications of CLD and its early recognition is of paramount importance. Though liver biopsy remains the gold standard for diagnosing liver fibrosis and upper gastrointestinal (GI) endoscopy plays an important role in diagnosing different findings of portal hypertension, various noninvasive methods like FibroScan are being increasingly used to diagnose liver fibrosis.
View Article and Find Full Text PDFThis study presents a halide exchange mediated cation exchange strategy for a room temperature doping of trivalent lanthanide cations (Ln) in cesium lead halide (CsPbX) nanoparticles (NPs). Post-synthetic addition of LnCl [Ln = Nd, Sm, Eu, Tb, Dy, and Yb] to a solution of CsPbBr NPs generates the corresponding lanthanide doped NPs which display host sensitized Ln emission. Structural and spectroscopic characterizations indicate a successful halide exchange and substitutional displacement of Pb by Ln.
View Article and Find Full Text PDFThis study was aimed to evaluate eggplant's growth-enhancing activity of chlorpyrifos and diazinon-degrading endophytic and rhizospheric soil bacteria isolated from cauliflower and tomato roots and the rhizospheric soil of rice roots, respectively. The identified endophytes belong to the Acinetobacter, Enterobacter and Klebsiella genera, while rhizospheric soil isolates belong to Pantoea, Acinetobacter, Kosakonia, Morganella, Enterobacter, and Klebsiella genera with species variation and genetic distances. All the strain's consumed 100% (50 mg/5 mL) chlorpyrifos and diazinon after 14 days of exposure, except for Pantoea sp.
View Article and Find Full Text PDFKlebsiella variicola is generally known as endophyte as well as lignocellulose-degrading strain. However, their roles in goat omasum along with lignocellulolytic genetic repertoire are not yet explored. In this study, five different pectin-degrading bacteria were isolated from a healthy goat omasum.
View Article and Find Full Text PDFThis study presents a post-synthetic ligand modification strategy for the generation of chiroptically active, blue emitting CsPbBr nanoparticles (NPs) - an expansion to the library of 3D chiral perovskite nanomaterials. Addition of [- and -] 1-phenylethylamine, 1-(1-naphthyl)ethylamine, or 2-aminooctane to the synthesized CsPbBr NPs is shown to induce Cotton effects in the NP first exciton transition, suggestive of a successful electronic coupling between the chiral ligands and the NPs. The availability of these chiral CsPbBr NPs thrusts them into the forefront of perovskite nanomaterials for examining the implications of the chiral induced spin selectivity (CISS) effect and other applications in spintronics.
View Article and Find Full Text PDFThe approved Pfizer and Moderna mRNA vaccines are well known to induce serum antibody responses to the SARS-CoV-2 Spike (S)-protein. However, their abilities to elicit mucosal immune responses have not been reported. Saliva antibodies represent mucosal responses that may be relevant to how mRNA vaccines prevent oral and nasal SARS-CoV-2 transmission.
View Article and Find Full Text PDFVaccines are critical for curtailing the COVID-19 pandemic (1, 2). In the USA, two highly protective mRNA vaccines are available: BNT162b2 from Pfizer/BioNTech and mRNA-1273 from Moderna (3, 4). These vaccines induce antibodies to the SARS-CoV-2 S-protein, including neutralizing antibodies (NAbs) predominantly directed against the Receptor Binding Domain (RBD) (1-4).
View Article and Find Full Text PDFTriple-negative breast cancer (TNBC) is a highly aggressive and metastatic subtype of breast cancer showing non-responsiveness to most available therapeutic options. Therefore, smart therapeutic approaches to selectively transport and target TNBCs are required. Herein, we developed thymoquinone (TQ)-loaded, hyaluronic acid (HA)-conjugated Pluronic® P123 and F127 copolymer nanoparticles (HA-TQ-Nps) as a selective drug-carrying vehicle to deliver anticancer phytochemical TQ to TNBC cells.
View Article and Find Full Text PDFThis work investigates the photoluminescence characteristics where cadmium selenide (CdSe) and zinc sulfide (ZnS) nanoparticles are treated post-synthetically by the trivalent lanthanide cations (Ln) [Ln = Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb] separately to form either CdSe/Ln or ZnS/Ln nanoparticles. Host sensitized Ln emission was found to be present only in CdSe/Eu, CdSe/Tb, ZnS/Eu, ZnS/Tb and ZnS/Yb nanoparticles. In all the cases tuning of emission of the nanoparticles has been observed, irrespective of the presence or absence of host sensitization.
View Article and Find Full Text PDFA systematic comparison of the Ln [Ln = Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb] photoluminescence in doped tin dioxide [Sn(Ln)O] and doped titanium dioxide [Ti(Ln)O] nanoparticles shows that the emission efficiency of trivalent lanthanide cations (Ln) in an oxide matrix can be improved by change of the cation site symmetry. An analysis of Ln emission quantum yield and asymmetry ratio is used to identify the importance of symmetry breaking around the dopant site for enhancing the Ln emission intensity. These findings identify an important criterion for engineering the luminescence intensity of dopant ions in semiconductor nanoparticle-based luminophores, which goes beyond the primary criterion of engineering the relative positions of the dopant energy levels with respect to the band edges of the host nanoparticle matrix.
View Article and Find Full Text PDFThis work reports the photophysical properties of 1-thioglycerol capped hydrophilic terbium cation incorporated (doped) zinc sulfide [Zn(Tb)S] nanoparticles, which have been post-synthetically modified using Pb [Zn(Tb)S/Pb] under ambient conditions with [Zn(Tb)S] : [Pb] = 1 : 10-1 : 10, essentially providing a scenario with low to heavy co-doping and ultimately the possibility of forming a material of different chemical identity. The effects of selected concentrations of [Zn(Tb)S] : [M ] = 1 : 1 and 1 : 10 have also been evaluated for the post-synthetic addition of Hg, Cd, Ca, Mg, Na and K. The broad zinc sulfide nanoparticle and sharp Tb emission have different dependence on the relative reactant concentration, with cation identity playing a significant role.
View Article and Find Full Text PDFThe native-like, soluble SOSIP.664 trimer based on the BG505 clade A env gene of HIV-1 is immunogenic in various animal species, of which the most studied are rabbits and rhesus macaques. The trimer induces autologous neutralizing antibodies (NAbs) consistently but at a wide range of titers and with incompletely determined specificities.
View Article and Find Full Text PDFThis work reports the host (semiconductor nanoparticles) sensitized dopant (lanthanides, Ln) photoluminescence in near band gap matched Sn(Ln)O and Zn(Ln)S [Ln = Sm, Tb] nanoparticles to address the importance of the nanoparticle identity and absolute band gap in the underlying process. While the sensitization was evident in the Sn(Sm)O and Zn(Tb)S nanoparticles, the same was not observed in the Sn(Tb)O and Zn(Sm)S nanoparticles. This observation stresses the importance of nanoparticle identity as the determining factor in realizing the host-sensitized dopant photoluminescence and provides important insight into developing novel doped inorganic nanoparticle-based optical materials.
View Article and Find Full Text PDFA challenge for HIV-1 immunogen design is the difficulty of inducing neutralizing antibodies (NAbs) against neutralization-resistant (tier 2) viruses that dominate human transmissions. We show that a soluble recombinant HIV-1 envelope glycoprotein trimer that adopts a native conformation, BG505 SOSIP.664, induced NAbs potently against the sequence-matched tier 2 virus in rabbits and similar but weaker responses in macaques.
View Article and Find Full Text PDFGenetic ablation of the ferrireductase STEAP3, also known as TSAP6, leads to severe microcytic and hypochromic red cells with moderate anemia in the mouse. However, the mechanism leading to anemia is poorly understood. Previous results indicate that TSAP6/Steap3 is a regulator of exosome secretion.
View Article and Find Full Text PDFProtein 4.1R was first identified in the erythrocyte membrane skeleton. It is now known that the protein is expressed in a variety of epithelial cell lines and in the epithelia of many tissues, including the small intestine.
View Article and Find Full Text PDFProtein 4.1G is a member of the protein 4.1 family, which in general serves as adaptors linking transmembrane proteins to the cytoskeleton.
View Article and Find Full Text PDFProtein 4.1R (4.1R) is the prototypical member of the protein 4.
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