The charge transfer kinetics of the catalyst particles play a key role in advanced oxidation processes (AOP) for the complete destruction of recalcitrant and persistent contaminants in water. Here, a significant improvement in the photocatalytic performance is observed in the Single-Walled Carbon Nanotube (SWCNT)-ZnO heterostructure photocatalyst. The charge transfer dynamics and factors affecting AOP are studied using ZnO nanoparticles self-assembled onto three electronically different SWCNTs (metallic, semiconducting, and pristine) via the precipitation method, introducing a heterojunction interface.
View Article and Find Full Text PDFThe increasing disposal of dyes and face-mask propel to hunt for a solution to fight water pollution while assisting sustainability. This research overcomes the key challenges associated with implementing photocatalytic water treatment by using natural sunlight active photocatalyst, changing slurry system, eliminating the use of external triggering sources, and reusing face-mask fabric coated with ZnO to act as a floating photocatalyst. Unique morphological structures-cauliflower, hydrangea, and petals-likes are obtained with the variation in synthesis medium (Diethylene glycol (DEG), N, N-dimethyl formamide (DMF), HO) and methods (precipitation, solvothermal) which are found to be dependent on the solvent properties.
View Article and Find Full Text PDFNoncovalent functionalization of single-walled carbon nanotubes (SWCNT) by semiconducting oxides is a majorly sought technique to retain individual properties while creating a synergetic effect for an efficient heterostructure charge transfer. Three types of electronically and optically different SWCNTs: metallic (m), semiconducting (s), and pristine (p) are functionalized by ZnO using a facile sonication method. The physicochemical and morphological properties of the ZnO-functionalized SWCNTs, m-SWCNT+ZnO, s-SWCNT+ZnO, and p-SWCNT+ZnO, are analyzed by advanced characterization techniques.
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