Recent advances in heavier group 15 (P, As, Sb, Bi) radical chemistry - frameworks, small molecule reactivity, and catalysis.

Main group radical chemistry has been a targeted research area for several decades. With growing examples of phosphorus radicals, even heavier pnictogen radicals including arsenic, antimony, and bismuth have also become important targets. A diverse framework of group 15 radicals has been reported in the 21st century and is covered herein.