In photovoltaics, perovskite solar cells (PSCs) have shown efficiency improvement with scalable and low-cost fabrication. This work investigates the additions of surfactants to PSCs during and after cell fabrication, and how these surfactants enhance the performance of both PSCs and hybrid PSCs. Various types of surfactants were surveyed, including amphoteric, cationic, and non-ionic, in addition to other chemicals that are showing surfactant-like behavior.
View Article and Find Full Text PDFDiabetes mellitus is a prevalent disease with a rapidly increasing incidence projected worldwide, affecting both industrialized and developing regions. Effective diabetes management requires precise therapeutic strategies, primarily through self-monitoring of blood glucose levels to achieve tight glycemic control, thereby mitigating the risk of severe complications. In recent years, there have been significant advancements in non-invasive techniques for measuring blood glucose using photoacoustic spectroscopy (PAS), as it shows great promise for the detection of glucose using the infrared region (e.
View Article and Find Full Text PDFOrganometal halide perovskite (OHP) composites are flexible and easy to synthesize, making them ideal for ambient mechanical energy harvesting. Yet, the output current density from the piezoelectric nanogenerators (PENGs) remains orders of magnitude lower than their ceramic counterparts. In prior composites, high permittivity nanoparticles enhance the dielectric constant (ϵ) but reduce the dielectric strength (E).
View Article and Find Full Text PDFInGaN/GaN micro-light-emitting diodes (micro-LEDs) with a metal-insulator-semiconductor (MIS) structure on the sidewall are proposed to improve efficiency. In this MIS structure, a sidewall electrode is deposited on the insulating layer-coated sidewall of the device mesa between a cathode on the bottom and an anode on the top. Electroluminescence (EL) measurements of fabricated devices with a mesa diameter of 10 μm show that the application of negative biases on the sidewall electrode can increase the device external quantum efficiency (EQE).
View Article and Find Full Text PDFThis study explored the potential of FeO, SnFeO, and CoFeO nanoparticles as larvicidal and adulticidal agents against () larvae and adults, which are vectors for various diseases. This research involved the synthesis of these nanoparticles using the coprecipitate method. The results indicate that CoFeO nanoparticles are the most effective in both larvicidal and adulticidal activities, with complete mortality achieved after 96 h of exposure.
View Article and Find Full Text PDFIndium arsenide (InAs) quantum dots (QDs) grown by molecular beam epitaxy (EBM) on gallium arsenide (GaAs) substrates have exhibited quantized charge-trapping characteristics. An electric charge can be injected in a single QD by a gold-coated AFM nano-probe placed directly on it using a conductive-mode atomic force microscope (C-AFM). The results revealed separate current-voltage (-) curves during consecutive measurements, where the turn-on voltages measured at the subsequent voltage sweeps are incrementally lower than that at the initial sweep.
View Article and Find Full Text PDFEnhancing the output power of triboelectric nanogenerators (TENGs) requires the creation of micro or nano-features on polymeric triboelectric surfaces to increase the TENGs' effective contact area and, therefore, output power. We deploy a novel bench-top fabrication method called dynamic Scanning Probe Lithography (d-SPL) to fabricate massive arrays of uniform 1 cm long and 2.5 µm wide nano-features comprising a 600 nm deep groove (NG) and a 600 nm high triangular prism (NTP).
View Article and Find Full Text PDFThe prevalence of diabetes is rapidly increasing worldwide and can lead to a range of severe health complications that have the potential to be life-threatening. Patients need to monitor and control blood glucose levels as it has no cure. The development of non-invasive techniques for the measurement of blood glucose based on photoacoustic spectroscopy (PAS) has advanced tremendously in the last couple of years.
View Article and Find Full Text PDFThe combination of mid-infrared and photoacoustic spectroscopy has shown promising developments as a substitute for invasive glucose detection technology. A dual single-wavelength quantum cascade laser system has been developed using photoacoustic spectroscopy for noninvasive glucose monitoring. Biomedical skin phantoms with similar properties to human skin have been prepared with blood components at different glucose concentrations as test models for the setup.
View Article and Find Full Text PDFRegulating the strain of inorganic perovskites has emerged as a critical approach to control their electronic and optical properties. Here, an alternative strategy to further control the piezoelectric properties by substituting the halogen atom (I/Br) in the CsPbX perovskite (X = Cl, Br) structure is adopted. A series of piezoelectric materials with excellent piezoelectric coefficients (d ) are unveiled.
View Article and Find Full Text PDFPiezoelectric materials convert between mechanical and electrical energy and are a basis for self-powered electronics. Current piezoelectrics exhibit either large charge (d) or voltage (g) coefficients but not both simultaneously, and yet the maximum energy density for energy harvesting is determined by the transduction coefficient: d*g. In prior piezoelectrics, an increase in polarization usually accompanies a dramatic rise in the dielectric constant, resulting in trade off between d and g.
View Article and Find Full Text PDFPoint-of-care testing (POCT) of clinical biomarkers is critical to health monitoring and timely treatment, yet biosensing assays capable of detecting biomarkers without the need for costly external equipment and reagents are limited. Blood-based assays are, specifically, challenging as blood collection is invasive and follow-upprocessing is required. Here, we report a versatile assay that employs hydrogel microneedles (HMNs) to extract interstitial fluid (ISF), in a minimally invasive manner integrated with graphene oxide-nucleic acid (GO.
View Article and Find Full Text PDFReversible lasing performance degradation is investigated on an uncoated actively- biased GaAs/AlGaAs mid-infrared quantum cascade laser (MIR-QCL) facet. The surface temperature rises (ΔT) on the MIR QCL are characterized before and after the device undergoes an accelerated aging burn-in test, followed by hydrogen plasma treatment. The data is visualized by spatially resolved time-domain thermoreflectance (SR-TDTR) microscopy.
View Article and Find Full Text PDFThe realization of a semiconductor near-unity absorber in the infrared will provide new capabilities to transform applications in sensing, health, imaging, and quantum information science, especially where portability is required. Typically, commercially available portable single-photon detectors in the infrared are made from bulk semiconductors and have efficiencies well below unity. Here, we design a novel semiconductor nanowire metamaterial, and show that by carefully arranging an InGaAs nanowire array and by controlling their shape, we demonstrate near-unity absorption efficiency at room temperature.
View Article and Find Full Text PDFHalide perovskite materials have been recently recognized as promising materials for piezoelectric nanogenerators (PENGs) due to their potentially strong ferroelectricity and piezoelectricity. Here, we report a new method using a poly(vinylidene fluoride) (PVDF) polymer to achieve excellent long-term stable black γ-phase CsPbI and explore the piezoelectric performance on a CsPbI@PVDF composite film. The PVDF-stabilized black-phase CsPbI perovskite composite film can be stable under ambient conditions for more than 60 days and over 24 h while heated at 80 °C.
View Article and Find Full Text PDFAccording to the International Diabetes Federation, 530 million people worldwide have diabetes, with more than 6.7 million reported deaths in 2021. Monitoring blood glucose levels is essential for individuals with diabetes, and developing noninvasive monitors has been a long-standing aspiration in diabetes management.
View Article and Find Full Text PDFACS Appl Mater Interfaces
February 2022
In this work, fluorescent solid carbon dots (CDs) welcome a new member, namely anhydride-terminated CDs, which have a photoluminescence quantum yield (PLQY) of 28% for orange-emitted CDs at 580 nm in powder form. For the first time, we revealed that the electronic coupling of the functional groups should be a crucial factor affecting the optical properties of solid CDs. Due to the negligible hydrogen bonding interaction between the anhydride groups, the electronic coupling of excitons between neighboring anhydride groups is weak, leading to a high PLQY of 28% and an immobile emission peak at 580 nm in solid state.
View Article and Find Full Text PDFDespite advances in the development of individual nanogenerators, the level of output energy generation must be increased to meet the demands of commercial electronic systems and to broaden their scope of application. To harvest low-frequency ambient mechanical energy more efficiently, we proposed a highly integrated hybridized piezoelectric-triboelectric-electromagnetic (tristate) nanogenerator in a uniaxial structure. In its highly integrated approach, a piezoelectric nanogenerator (PENG) based on CsPbBr (cesium lead bromide) nanoparticles (NPs) and poly(dimethylsiloxane) (PDMS) nanocomposite was fabricated on a triboelectrically negative nanostructured polyimide (PI) substrate.
View Article and Find Full Text PDFClouds in the sky pass almost 80% of ultraviolet (UV) radiation to the earth's surface, which has a significant impact on humankind. Conventional UV photodetectors (PDs) require an external battery, which not only increases the device size but also has a limited life span and maintenance costs can be prohibitively expensive. An alternative and more technically-sound solution would be the use of self-powered UV PDs that can operate independently, eliminating the need for an external source.
View Article and Find Full Text PDFThe growing demands for optical anti-counterfeiting technology require the development of new environmentally friendly materials with single component, multimodal fluorescence and high stability. Herein, the Bi/Sb codoped CsAgNaInCl lead-free double perovskite material is reported as an efficient multimodal luminescence material with excitation-wavelength-dependent emission. When excited by 360 nm UV light, dual-emission is observed at 455 and 560 nm, which comes from the P-S transition of Sb ions and self-trapped excitons (STEs), respectively.
View Article and Find Full Text PDFAll-inorganic cesium lead halide perovskite nanocrystals (NCs) are quite promising materials for emission-based applications. However, the intrinsic toxicity of lead, as well as the weak stability, remains to be resolved. Exploring more and more types of lead-free NCs with high photoluminescence quantum yields (PLQYs) and high stability is a fundamental task.
View Article and Find Full Text PDFWe correct three typographical errors in our published paper [Opt. Express26, 9194 (2018)10.1364/OE.
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