Extra virgin olive oil (EVO) is among the most counterfeit foodstuffs in the present market. The Italian production is with no doubt one of the most valuable and therefore mostly counterfeit, due to the difficulty in checking the geographic provenance of olives. In order to provide a way for verifying the provenance of EVO, the role of microelements and, in particular, of lanthanides in the oil production chain has been studied.
View Article and Find Full Text PDFSalicornia veneta (Pignatti et Lausi) is an extreme halophyte living in salt marsh where NaCl concentration may be as high as 1 M. Here we report on the isolation and characterization of a PSII preparation obtained by Triton X-100 solubilisation of the thylakoid membrane. By a combination of gel electrophoresis, immunoblotting and mass spectrometry, the depletion of a number of PSII proteins such as PsbQ, PsbM and PsbT was highlighted.
View Article and Find Full Text PDFThe traceability and authentication of milk were studied using trace and ultratrace elements as chemical markers. Among these variables, the group of lanthanides resulted in being particularly useful for this purpose as a result of their homogeneous distribution inside milk, which showed on the contrary to be intrinsically inhomogeneous from the elemental point of view. Using in this pilot study milk samples from a factory in Piedmont (Italy), we demonstrated that the distribution of lanthanides can be used as a fingerprint to put into relation the soil of the pasture land on which cows graze and the bottled milk produced in the factory.
View Article and Find Full Text PDFComp Biochem Physiol C Toxicol Pharmacol
December 2016
Numerous studies on molluscs have been carried out to clarify the physiological roles of haemolymph serum proteins and haemocytes. However, little is known about the presence and functional role of the serum metabolites. In this study, Nuclear Magnetic Resonance (NMR) was used to assess whether changes of the metabolic profile of Mytilus galloprovincialis haemolymph may reflect alterations of the physiological status of the organisms due to environmental stressors, namely copper and temperature.
View Article and Find Full Text PDFHigh nitrogen concentration in wastewaters requires treatments to prevent the risks of eutrophication in rivers, lakes and coastal waters. The use of constructed wetlands is one of the possible approaches to lower nitrate concentration in wastewaters. Beyond supporting the growth of the bacteria operating denitrification, plants can directly take up nitrogen.
View Article and Find Full Text PDFSulfonated aromatic pollutants such as 1,5-naphthalenedisulfonic acid (NDS or Armstrong's acid) are persistent compounds and thus resist environmental breakdown and microbial treatment. This study investigated the photo-oxidative degradation of such a persistent polar pollutant in the absence and presence of H2O2. The degradation of aqueous NDS solutions by photolysis was found to be efficient only in the presence of H2O2.
View Article and Find Full Text PDFHazelnut is one of the most important items in high-quality food products from Piedmont, Italy. The 'Tonda Gentile delle Langhe' (TGL) variety is acknowledged all over the world as the best one, and it is particularly appreciated when used to provide flavor in chocolate products. Authentication and/or traceability studies must therefore be developed to safeguard this variety against fraud, which can occur when the product is partially or totally substituted with hazelnuts of lower quality.
View Article and Find Full Text PDFSulfonated aromatic pollutants such as Armstrong's acid, or 1,5-naphthalenedisulfonic acid (NDS), are recalcitrant to environmental breakdown and microbial treatment. This study investigated the effects of H(2)O(2) concentration, pH, microwave (MW) power and irradiation time on the oxidative degradation of NDS in aqueous solutions. The formation of hydroxyl radicals as the active oxidant was confirmed by electron paramagnetic resonance spin trapping.
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