DOSIMETRY WITH THE ABILITY TO DISTINGUISH PULSED AND NON-PULSED DOSE CONTRIBUTIONS.

The concept of an active dosimetry system for pulsed radiation dose rate measurements is presented. Real-time distinction of pulsed and non-pulsed radiation contributions is based on the time structure of a single interaction. A fast tissue equivalent plastic scintillator is exploited to minimize the pile-up effect influence on absorbed energy measurements.

Cyclic alkyl amino carbene (CAAC) ruthenium complexes as remarkably active catalysts for ethenolysis.

An expanded family of ruthenium-based metathesis catalysts bearing cyclic alkyl amino carbene (CAAC) ligands was prepared. These catalysts exhibited exceptional activity in the ethenolysis of the seed-oil derivative methyl oleate. In many cases, catalyst turnover numbers (TONs) of more than 100,000 were achieved, at a catalyst loading of only 3 ppm.

Trinuclear gold clusters supported by cyclic (alkyl)(amino)carbene ligands: mimics for gold heterogeneous catalysts.

The synthesis of air- and moisture-stable trinuclear mixed-valence gold(I)/gold(0) clusters is described. They promote the catalytic carbonylation of amines under relatively mild conditions. The synthetic route leading to the trinuclear clusters involves a simple ligand exchange from the readily available μ(3)-oxo-[(Ph3 PAu)3O](+) complex.

Isolation of neutral mononuclear copper complexes stabilized by two cyclic (alkyl)(amino)carbenes.

Two (cAAC)2Cu complexes, featuring a two-coordinate copper atom in the formal oxidation state zero, were prepared by reducing (Et2-cAAC)2Cu(+)I(-) with metallic sodium in THF, and by a one-pot synthesis using Me2-cAAC, Cu(II)Cl2, and KC8 in toluene in a molar ratio of 2:1:2, respectively. Both complexes are highly air and moisture sensitive but can be stored in the solid state for a month at room temperature. DFT calculations showed that in these complexes the copper center has a d(10) electronic configuration and the unpaired electron is delocalized over two carbene carbon atoms.

Isolation of a carborane-fused triazole radical anion.

Outside the cage: A change in the redox properties of a triazole fused to a carborane anion through methylation to form a zwitterion enabled facile chemical reduction of the compound to an isolable triazole radical anion (see structure: C gray, H white, N blue, B brown, Cl green). The radical anion is stabilized by kinetic protection by the chlorinated carborane and the delocalization of spin density throughout the exo-cluster π system.

Authenticity: is it real or is it marketing?

Marty Echt, the new head of marketing at Hunsk Engines, is determined to bring the motorcycle maker back to its roots. He says it's not enough to project authenticity to customers--employees must personally subscribe to the brand's values. Should the company's CEO support Marty's "real deal" vision? Five experts comment on this fictional case study.