Effect of additives, ball milling and isotopic exchange in porous magnesium borohydride.

Magnesium borohydride (Mg(BH)) is a promising material for solid state hydrogen storage. However, the predicted reversible hydrogen sorption properties at moderate temperatures have not been reached due to sluggish hydrogen sorption kinetics. Hydrogen (H) → deuterium (D) exchange experiments can contribute to the understanding of the stability of the BH anion.

Pd-Cu-M (M = Y, Ti, Zr, V, Nb, and Ni) Alloys for the Hydrogen Separation Membrane.

Self-supported fcc Pd-Cu-M (M = Y, Ti, Zr, V, Nb, and Ni) alloys were studied as potential hydrogen purification membranes. The effects of small additions (1-2.6 at.

High-Pressure Raman and Calorimetry Studies of Vanadium(III) Alkyl Hydrides for Kubas-Type Hydrogen Storage.

Reversible hydrogen storage under ambient conditions has been identified as a major bottleneck in enabling a future hydrogen economy. Herein, we report an amorphous vanadium(III) alkyl hydride gel that binds hydrogen through the Kubas interaction. The material possesses a gravimetric adsorption capacity of 5.

Thermodynamically neutral Kubas-type hydrogen storage using amorphous Cr(III) alkyl hydride gels.

In this paper we present amorphous chromium(III) hydride gels that show promise as reversible room temperature hydrogen storage materials with potential for exploitation in mobile applications. The material uses hydride ligands as a light weight structural feature to link chromium(III) metal centres together which act as binding sites for further dihydrogen molecules via the Kubas interaction, the mode of hydrogen binding confirmed by high pressure Raman spectroscopy. The best material possesses a reversible gravimetric storage of 5.

Characterisation of porous hydrogen storage materials: carbons, zeolites, MOFs and PIMs.

Porous materials adsorb H2 through physisorption, a process which typically has a rather low enthalpy of adsorption (e.g. ca.

Nitrogen and hydrogen adsorption by an organic microporous crystal.

Quick on the uptake: Following its identification during a targeted search, the intriguing crystal structure of 3,3',4,4'-tetra(trimethylsilylethynyl)biphenyl was investigated. Simple removal of the included solvent provides an organic crystal with an open microporous structure that has a striking similarity to that of zeolite A (see picture). Reversible adsorption of nitrogen and hydrogen gases at 77 K confirms that the microporosity is permanent.

The potential of organic polymer-based hydrogen storage materials.

The challenge of storing hydrogen at high volumetric and gravimetric density for automotive applications has prompted investigations into the potential of cryo-adsorption on the internal surface area of microporous organic polymers. A range of Polymers of Intrinsic Microporosity (PIMs) has been studied, the best PIM to date (a network-PIM incorporating a triptycene subunit) taking up 2.7% H(2) by mass at 10 bar/77 K.

A triptycene-based polymer of intrinsic microposity that displays enhanced surface area and hydrogen adsorption.

A novel triptycene-based polymer of intrinsic microporosity (Trip-PIM) displays enhanced surface area (1065 m2 g(-1)) and reversibly adsorbs 1.65% hydrogen by mass at 1 bar/77 K and 2.71% at 10 bar/77 K.

Chemical activation of MgH2; a new route to superior hydrogen storage materials.

We report the discovery of a new, chemical route for 'activating' the hydrogen store MgH2, that results in highly effective hydrogen uptake/release characteristics, comparable to those obtained from mechanically-milled material.

Office-based lower airway endoscopy in pediatric patients.

Background: Office-based evaluation of the lower airway in adults with only topical anesthetics has been well documented. This study was performed to assess the feasibility of performing office-based lower airway endoscopy in a pediatric population.

Design: One hundred five consecutive pediatric patients requiring flexible laryngoscopy were studied.

Quality of life assessment in nasal airway obstruction.

Objectives/hypothesis: Quality of life (QOL) assessment of patients with nasal obstruction has not been well studied. The objectives of the study were to determine the QOL of patients with nasal obstruction, to identify baseline variables predictive of patients' QOL, and to examine the relationship of QOL scores with patient assessment of nasal obstruction.

Study Design: Preliminary, cross-sectional study of a larger, prospective investigation.

Chronic sinonasal disease in patients with inflammatory bowel disease.

Background: The objective of this study was to explore the possible relationship between inflammatory bowel disease (IBD) and chronic sinonasal disease.

Methods: A cross-sectional study was undertaken of 241 patients with Crohn's disease (CD) or ulcerative colitis from a tertiary medical center IBD clinic. Patient demographic data and information regarding IBD diagnosis and management, sinonasal disease diagnosis and management, and complications related to these diagnoses were gathered by retrospective chart review and a standardized patient survey.

Plastic bronchitis: an unusual bronchoscopic challenge associated with congenital heart disease repair.

Plastic bronchitis is a rare disorder characterized by the formation of branching mucoid bronchial casts. Several pathophysiologic conditions are associated with development of these intrabronchial casts, including congenital heart defects. The management of plastic bronchitis presents an unusual and interesting bronchoscopic challenge.

Perspectives in laryngopharyngeal reflux: an international survey.

Objectives: Although data exists to support the relationship between laryngopharyngeal reflux (LPR) and laryngitis, there is variability among otolaryngologists regarding the methods and criteria used to make the diagnosis. This study was undertaken to discern the current attitudes and practices of a select cohort of otolaryngologists in regards to LPR.

Methods: Four hundred fifteen surveys were mailed to members of the American Broncho-Esophagological Association.