Controlling Thin Film Morphology Formation during Gas Quenching of Slot-Die Coated Perovskite Solar Modules.

Transferring record power conversion efficiency (PCE) >25% of spin coated perovskite solar cells (PSCs) from the laboratory scale to large-area photovoltaic modules requires significant advances in scalable fabrication techniques. In this work, we demonstrate the fundamental interrelation between drying dynamics of slot-die coated precursor solution thin films and the quality of resulting slot-die coated gas-quenched polycrystalline perovskite thin films. Well-defined drying conditions are established using a temperature-stabilized, movable table and a flow-controlled, oblique impinging slot nozzle purged with nitrogen.

InO:H-Based Hole-Transport-Layer-Free Tin/Lead Perovskite Solar Cells for Efficient Four-Terminal All-Perovskite Tandem Solar Cells.

Narrow-band gap (NBG) Sn-Pb perovskites with band gaps of ∼1.2 eV, which correspond to a broad photon absorption range up to ∼1033 nm, are highly promising candidates for bottom solar cells in all-perovskite tandem photovoltaics. To exploit their potential, avoiding optical losses in the top layer stacks of the tandem configuration is essential.