Optimizing surface water quality parameters in monitoring networks in a developing sub-tropical region with high anthropogenic pressure (São Paulo State Brazil).

Efficient water quality monitoring is a central aspect of water resources management, especially in developing countries, where water quality is under high anthropogenic pressure and resources for monitoring are usually limited. Here, we evaluated an alternative to optimize water quality parameters (WQPs) in the water quality monitoring network (WQMN) of the most populous state in Brazil (São Paulo State). We focused on the monitoring goal of identifying water quality temporal trends, selecting WQPs with high statistical explanatory power and those that were particularly sensitive to natural and anthropogenic perturbations.

Dam removal effects on carbon processing in a mountainous Mediterranean stream.

The global prevalence of obsolete or unsafe old dams necessitates the development of effective restoration approaches and expanded knowledge in this field. This study evaluates the effects of dam removal on carbon processing by measuring key ecosystem functions - organic matter decomposition, whole-reach metabolism, and gaseous carbon fluxes - in a mountainous Mediterranean stream. We compared these functions among three reaches: one where a dam was removed (restored), one with an intact dam (impacted), and one in natural conditions (reference).

Sampling frequency optimization of the water quality monitoring network in São Paulo State (Brazil) towards adaptive monitoring in a developing country.

Water quality monitoring networks (WQMNs) that capture both the temporal and spatial dimensions are essential to provide reliable data for assessing water quality trends in surface waters, as well as for supporting initiatives to control anthropogenic activities. Meeting these monitoring goals as efficiently as possible is crucial, especially in developing countries where the financial resources are limited and the water quality degradation is accelerating. Here, we asked if sampling frequency could be reduced while maintaining the same degree of information as with bimonthly sampling in the São Paulo State (Brazil) WQMN.

Adsorption of recalcitrant contaminants of emerging concern onto activated carbon: A laboratory and pilot-scale study.

According to the World Health Organization (WHO), the definition of water quality indicators, including contaminants of emerging concern (CECs), associated with the development of multi-barrier approaches for wastewater treatment, are crucial steps towards direct potable reuse of water. The aims of this study were 1) quantifying twelve CECs (including pharmaceutical, stimulant, and artificial sweetener compounds) in both untreated and treated wastewater samples in a Brazilian wastewater treatment plant (WWTP) using bidimensional liquid chromatography coupled with tandem mass spectrometry, allowing the selection of five marker (i.e.

Effect of three commercial algaecides on cyanobacteria and microcystin-LR: implications for drinking water treatment using activated carbon.

Toxic cyanobacterial blooms in aquatic ecosystems are associated to both public health and environmental concerns worldwide. Depending on the treatment technologies used, the removal capacity of cyanotoxins by drinking water treatment plants (DWTPs) is not sufficient to reach safe levels in drinking water. Likewise, controlling these blooms with algaecide may impair the efficiency of DWTPs due to the possible lysis of cyanobacterial cells and consequent release of cyanotoxins.

Smartphone-based spectrometry system as a prescreening assessment of copper and iron for real time control of water pollution.

Due to anthropogenic actions, the presence of pollutants in water bodies, such as toxic metals, are increasingly negatively affecting water quality, biodiversity and sustainable goals worldwide. Therefore, decentralization of water pollution monitoring with low-cost devices, such as using smartphones, suggests an innovative green technology for in situ and real-time control. In this study, a Handheld Smartphone Spectrophotometry System (HSSS) was developed to estimate copper and iron concentration water samples.

COVID-19 and organisational resilience in Brazil's water sector.

The COVID-19 pandemic required a wide range of adaptations to the way that water sector operated globally. This paper looks into the impact of the COVID-19 pandemic on Brazilian water sector and evaluates the water sector's organisational resilience from the lens of water professionals. This study uses British Standard (BS 65000:2014)'s Resilience Maturity Scale method to evaluate organisational resilience in water sector under two defined scenarios of before and during the pandemic.

Methane concentrations and fluxes in agricultural and preserved tropical headwater streams.

Tropical streams have been intensively impacted by agricultural activities. Among the most important agricultural activities in Brazil, sugarcane production represents a large impact for economic development and for environmental conditions. Permeating sugarcane fields, several headwater streams can be affected by sugarcane cultivation, in special, aquatic biogeochemical cycles because of the deforestation, fertilization, crop residues and higher temperatures in the tropics.

Exposure to microcystin-LR in tropical reservoirs for water supply poses high risks for children and adults.

While the presence of microcystin-LR (MC-LR) in raw water from eutrophic reservoirs poses human health concerns, the risks associated with the ingestion of MC-LR in drinking water are not fully elucidated. We used a time series of MC-LR in raw water from tropical urban reservoirs in Brazil to estimate the hazard quotients (HQs) for non-carcinogenic health effects and the potential ingestion of MC-LR through drinking water. We considered scenarios of MC-LR removal in the drinking water treatment plants (DWTPs) of two supply systems (Cascata and Guarapiranga).

The Longitudinal Profile of a Stream Contaminated With 2,4-D and its Effects on Non-Target Species.

Pesticides can cause harmful effects to aquatic communities, even at concentrations below the threshold limit established as guidelines for the water bodies by environmental agencies. In this research, an input of the herbicide 2,4-dichlorophenoxyacetic acid (i.e.

Spatial optimization of the water quality monitoring network in São Paulo State (Brazil) to improve sampling efficiency and reduce bias in a developing sub-tropical region.

Water quality monitoring networks (WQMNs) are essential to provide good data for management decisions. Nevertheless, some WQMNs may not appropriately reflect the conditions of the water bodies and their temporal/spatial dimensions, more particularly in developing countries. Also, some WQMNs may use more resources to attain management goals than necessary and can be improved.

Competitive kinetics of adsorption onto activated carbon for emerging contaminants with contrasting physicochemical properties.

Activated carbon (AC) can be used for the removal of emerging contaminants (e.g., drugs) in water and wastewater treatment plants.

Characterizing Trophic State in Tropical/Subtropical Reservoirs: Deviations among Indexes in the Lower Latitudes.

Trophic state indexes (TSI) guide management strategies regarding eutrophication control worldwide. Such indexes usually consider chlorophyll-a (Chl-a), total phosphorus (TP), and Secchi disk depth (SDD) as independent variables for estimating aquatic productivity and the degree of impairment. TSIs for each of these components are frequently averaged to produce a single TSI value associated with a trophic state classification (e.

Towards urban resilience through Sustainable Drainage Systems: A multi-objective optimisation problem.

The necessity of incorporating a resilience-informed approach into urban planning and its decision-making is felt now more than any time previously, particularly in low and middle income countries. In order to achieve a successful transition to sustainable, resilient and cost-effective cities, there is a growing attention given to more effective integration of nature-based solutions, such as Sustainable Drainage Systems (SuDS), with other urban components. The experience of SuDS integration with urban planning, in developed cities, has proven to be an effective strategy with a wide range of advantages and lower costs.

The contribution of volunteer-based monitoring data to the assessment of harmful phytoplankton blooms in Brazilian urban streams.

Urban streams are vulnerable to a range of impacts, leading to the impairment of ecosystem services. However, studies on phytoplankton growth in tropical lotic systems are still limited. Citizen science approaches use trained volunteers to collect environmental data.

Micro and Macroscale Drivers of Nutrient Concentrations in Urban Streams in South, Central and North America.

Global metrics of land cover and land use provide a fundamental basis to examine the spatial variability of human-induced impacts on freshwater ecosystems. However, microscale processes and site specific conditions related to bank vegetation, pollution sources, adjacent land use and water uses can have important influences on ecosystem conditions, in particular in smaller tributary rivers. Compared to larger order rivers, these low-order streams and rivers are more numerous, yet often under-monitored.

Trophic State Evolution and Nutrient Trapping Capacity in a Transboundary Subtropical Reservoir: A 25-Year Study.

Artificial reservoirs have been used for drinking water supply, other human activities, flood control and pollution abatement worldwide, providing overall benefits to downstream water quality. Most reservoirs in Brazil were built during the 1970s, but their long-term patterns of trophic status, water chemistry, and nutrient removal are still not very well characterized. We aimed to evaluate water quality time series (1985-2010) data from the riverine and lacustrine zones of the transboundary Itaipu Reservoir (Brazil/Paraguay).

Quantification of phytoplankton bloom dynamics by citizen scientists in urban and peri-urban environments.

Freshwater ecosystems are severely threatened by urban development and agricultural intensification. Increased occurrence of algal blooms is a main issue, and the identification of local dynamics and drivers is hampered by a lack of field data. In this study, data from 13 cities (250 water bodies) were used to examine the capacity of trained community members to assess elevated phytoplankton densities in urban and peri-urban freshwater ecosystems.

Trends in nutrient and sediment retention in Great Plains reservoirs (USA).

Reservoirs are artificial ecosystems with physical, chemical, and biological transitional characteristics between rivers and lakes. Greater water retention time in reservoirs provides conditions for cycling materials inputs from upstream waters through sedimentation, biological assimilation and other biogeochemical processes. We investigated the effects of reservoirs on the water quantity and quality in the Great Plains (Kansas, USA), an area where little is known about these dominant hydrologic features.