Boosting the capacitive property of binary metal tellurium of MnCoTe/NiFeTe yarn coils-like through surface engineering for high-performance supercapacitors.

Improving the performance of electrode materials based on transition metals can significantly push advancements in energy storage devices. In this work, we offer a novel in situ tellurization approach to synthesize brand-new decorated yarn-coils MnCoTe/NiFeTe on a NiF (labeled MCTe/NFTe@NiF) which makes them attractive candidates for electrode materials in hybrid supercapacitors. At first, two consecutive hydrothermal methods were used to create electrode materials MnCo-LDH and MnCo-LDH/NiFe-LDH on nickel foam, respectively.

Easy and fast synthesis of MnCo-LDH yolk-shell spheres porous composites applied electrospinning nanofibers highly effective for extracting triazole fungicides.

Today, the wide utilization of triazole fungicides due to environmental damage and its side effects has raised global concern. Thus, in this investigation, polyacrylonitrile/MnCo-layered double hydroxides nanofiber was synthesized and applied as an effective and novel adsorbent at thin-film solid-phase micro-extraction technique for the quick and concurrent extraction of five triazole fungicides in fruit and vegetable samples before quantitative analysis by high-performance liquid chromatography-ultraviolet. The incorporation of MnCo-layered double hydroxides with porous structure and abundant functional groups in a polymer medium improves the extraction efficiency of nanofibers owing to hydrogen bonding and π-π interactions formed between analytes and synthesized nano-adsorbent.

In situ tellurization strategy for crafting nickel ditelluride/cobalt ditelluride hierarchical nanostructures: A leap forward in hybrid supercapacitor electrode materials.

Advancements in renewable energy conversion can be significantly propelled by optimizing the performance of transition-metal-based electrodes. In this study, we introduce an innovative, in situ tellurization strategy to synthesize novel, flower-like hierarchical structures of nickel ditelluride/cobalt ditelluride (NiTe/CoTe) on a nickel foam substrate (labeled as NF/FNCT), making them promising candidates for electrodes in hybrid supercapacitors. Initially, we utilized a hydrothermal method to create flower-like NiCo-layered double hydroxide (NiCo-LDH) nanoarrays on nickel foam (NF/FNCLDH).

In Vivo Microstructure Imaging in Oropharyngeal Squamous Cell Carcinoma Using the Random Walk With Barriers Model.

Background: Apparent diffusion coefficient is not specifically sensitive to tumor microstructure and therapy-induced cellular changes.

Purpose: To investigate time-dependent diffusion imaging with the short-time-limit random walk with barriers model (STL-RWBM) for quantifying microstructure parameters and early cancer cellular response to therapy.

Study Type: Prospective.

Development of electrospun nanofibers based on Poly (vinyl alcohol) for thin film solid-phase microextraction of antidepressant drugs in biological samples.

Today, antidepressants are widely used and it is important to determine their trace amounts due to harmful consequences. Here, a new nano sorbent was reported for the simultaneous extraction and determination of three types of antidepressant drugs (Clomipramine (CLO), Clozapine (CLZ), and Trimipramine (TRP) by the thin-film solid-phase micro-extraction (TFME-μSPE) method followed by the Gas Chromatography-flame ionization detector (GC-FID) analysis. So, the compound poly (vinyl alcohol) (PVA)/citric acid(CA)/β-cyclodextrin/BiS@g-CN nano sorbent was constructed by electrospinning technique.

Curcumin-Melamine For Solid-Phase Microextraction of Volatile Organic Compounds from Aqueous Samples.

The hybrid coating of curcumin and melamine was prepared by a simple electrochemical method. Some physical and chemical properties of the fiber were studied by several methods such as FT-IR, scanning electron microscopy and X-ray fluorescence spectroscopy. The fiber was stable at the inlet of a gas chromatograph at temperatures up to 280°C.

Does intramuscular ondansetron have an effect on intramuscular ketamine-associated vomiting in children? A prospective, randomized, double blind, controlled study.

Objective: This study was conducted to determine the effect of intramuscular ondansetron on ketamine-associated vomiting in children undergoing procedural sedation.

Methods: This randomized, double-blind, placebo-controlled, parallel-group clinical trial was conducted at the emergency departments of two university-affiliated tertiary care hospitals. Eligible participants included all 6-month to 16-year-old children who received IM ketamine for PSA in the ED.

Synthesis of NiGaS-rGO on nickel foam as advanced electrode for flexible solid-state supercapacitor with superior energy density.

Pseudocapacitive electrode materials employed in supercapacitors may bring in high energy density (ED) and specific capacitance (C), which are critical for their practical applications. Accordingly, logical design of advanced electrode materials is highly demanded to progress high-performance supercapacitors. Here, for the first time, we suggest a straightforward route for the synthesis of NiGaS-rGO as an advanced cathode material supported on nickel foam (NF) for employed in flexible solid-state asymmetric supercapacitors (FSASCs).

Highly efficient electrochemical determination of propylthiouracil in urine samples after selective electromembrane extraction by copper nanoparticles-decorated hollow fibers.

In this work, a novel, inexpensive and fast strategy was described for selective and effective extraction and determination of propylthiouracil (PTU) with a high polarity (log P = 1.2) based on electromembrane extraction (EME) followed by differential pulse voltammetry (DPV). For this purpose, copper nanoparticles (CuNPs)-decorated hollow fiber was used as the selective membrane for EME of PTU in urine samples.

Assessment of corrected flow time in carotid artery via point-of-care ultrasonography: Reference values and the influential factors.

Objective: Assessment of Corrected Flow Time (FTc) in carotid artery has been suggested recently as a measure of intravascular volume status. This study aimed to determine the reference values of FTc in carotid artery in a normal population.

Methods: A total number of 142 healthy volunteers (73 females and 69 males) with a mean age of 36.

Highly selective solid phase extraction and preconcentration of Azathioprine with nano-sized imprinted polymer based on multivariate optimization and its trace determination in biological and pharmaceutical samples.

In this research, for first time selective separation and determination of Azathioprine is demonstrated using molecularly imprinted polymer as the solid-phase extraction adsorbent, measured by spectrophotometry at λ 286nm. The selective molecularly imprinted polymer was produced using Azathioprine and methacrylic acid as a template molecule and monomer, respectively. A molecularly imprinted solid-phase extraction procedure was performed in column for the analyte from pharmaceutical and serum samples.

Clinical course teaching in transport of critically ill patients: Small group methods.

Critically ill patient transfer is potentially risky and may be lead to morbidity and mortality. Physicians' skill is very important for safe transport. We want to evaluate the effect of clinical course teaching on the promotion of physicians' abilities in the transport of critically ill patients.

Sonoelectrochemical Synthesis of Nano Zinc (II) Complexes with 9-Anthracenecarboxylic Acid: Effect of Current Density and Study of their Photophysical Properties.

A new zinc complex, [Zn (9-AC)] (1) (9-AC = 9-anthracenecarboxylic acid), was prepared via conventional electrochemical method in a fast and facile process and fully characterized by H NMR, C NMR, IR spectroscopy and elemental analysis. The nano structures of the same compound were successfully produced by a facile and environment-friendly sonoelectrochemical route at different current densities (0.5, 1.

Selective and sensitive speciation analysis of Cr(VI) and Cr(III), at sub-μgL levels in water samples by electrothermal atomic absorption spectrometry after electromembrane extraction.

In this work, electromembrane extraction in combination with electrothermal atomic absorption spectrometry (ET-AAS) was investigated for speciation, preconcentration and quantification of Cr(VI) and Cr(III) in water samples through the selective complexation of Cr(VI) with 1,5-diphenylcarbazide (DPC) as a complexing agent. DPC reduces Cr(VI) to Cr(III) ions and then Cr(III) species are extracted based on electrokinetic migration of their cationic complex (Cr(III)-DPC) toward the negative electrode placed in the hollow fiber. Also, once oxidized to Cr(VI), Cr(III) ions in initial sample were determined by this procedure.

An efficient approach to selective electromembrane extraction of naproxen by means of molecularly imprinted polymer-coated multi-walled carbon nanotubes-reinforced hollow fibers.

In this work, a novel microextraction technique using molecularly imprinted polymer-coated multi-walled carbon nanotubes (MIP-MWCNTs) in electromembrane extraction (EME) procedure is described. The method in combination with HPLC-UV was utilized to determine naproxen, as an acidic model drug, in urine, plasma and wastewater samples. For this purpose, MIP-MWCNTs were placed in the pores of polypropylene hollow fiber.

Impedometric monitoring of the behavior of the supported liquid membrane in electromembrane extraction systems: An insight into the origin of optimized experimental parameters.

Electromembrane extraction (EME) was carried out using a novel instrumentation capable of impedometric monitoring of the system during the extraction. This instrumentation involves a classical two-electrode assembly fed by two time-resolved potential functions, the first for the extraction of analyte and the second for obtaining the impedance information. The impedometric analysis of the system was achieved by Laplace transformation of the current recorded during the extraction.

Highly selective determination of amitriptyline using Nafion-AuNPs@branched polyethyleneimine-derived carbon hollow spheres in pharmaceutical drugs and biological fluids.

In this paper, AuNPs@Polyethyleneimine-derived carbon hollow spheres were synthesized by a versatile and facile method in three steps and successfully developed and validated as Amitriptyline sensor using cyclic voltammetry (CV), chronoamperometry (CA) and differential pulse voltammetry (DPV) methods. The characterization of the electrode surface has been carried out by means of scanning electron microscopy (SEM), transmission electron microscopy (TEM), x-ray diffraction (XRD), x-ray photo-electron spectrum (XPS), electrochemical impedance spectroscopy (EIS) and chronocoulometry (CC). The obtained negatively charged modified electrode was highly selective to Amitriptyline and it was shown a wide linear range from 0.

Cell Treatment for Stroke in Type Two Diabetic Rats Improves Vascular Permeability Measured by MRI.

Treatment of stroke with bone marrow stromal cells (BMSC) significantly enhances brain remodeling and improves neurological function in non-diabetic stroke rats. Diabetes is a major risk factor for stroke and induces neurovascular changes which may impact stroke therapy. Thus, it is necessary to test our hypothesis that the treatment of stroke with BMSC has therapeutic efficacy in the most common form of diabetes, type 2 diabetes mellitus (T2DM).

White matter changes after stroke in type 2 diabetic rats measured by diffusion magnetic resonance imaging.

Diffusion-related magnetic resonance imaging parametric maps may be employed to characterize white matter of brain. We hypothesize that entropy of diffusion anisotropy may be most effective for detecting therapeutic effects of bone marrow stromal cell treatment of ischemia in type 2 diabetes mellitus rats. Type 2 diabetes mellitus was induced in adult male Wistar rats.

Surfactant assisted pulsed two-phase electromembrane extraction followed by GC analysis for quantification of basic drugs in biological samples.

In this work, a simple and efficient surfactant assisted pulsed two-phase electromembrane extraction (SA-PEME) procedure combined with gas chromatography (GC) has been developed for the determination of alfentanil, sufentanil and methadone in various samples. It has been found that the addition of anionic surfactant causes the accumulation of the cationic analytes at the SLM/solution interface resulting in an easier transfer of the analytes into the organic phase. The method was accomplished with 1-octanol as the acceptor phase and supported liquid membrane (SLM) by means of an 80 V pulsed electrical driving force and the extraction time of 20 min.

Carotid artery corrected flow time measurement via bedside ultrasonography in monitoring volume status.

Purpose: The purpose of this study is to investigate the possible correlation between corrected flow time (FTc) in carotid artery and changes in volume status.

Materials And Methods: Ninety-three patients with end-stage renal failure who underwent fluid removal via hemodialysis were enrolled prospectively. The volume of fluid removed as well as prehemodialysis and posthemodialysis measures of FTc in the carotid artery, heart rate, and mean arterial pressure was evaluated.

Solid-phase microextraction of phthalate esters by a new coating based on a thermally stable polypyrrole/graphene oxide composite.

A novel polypyrole/graphene oxide coating was made by the electrochemical polymerization of pyrrole in the presence of sodium dodecyl sulfate and graphene oxide on a platinum wire. The prepared fiber has shown a good thermal stability up to 300°C. The fiber was applied to the direct solid-phase microextraction and gas chromatographic analysis of four phthalate esters.

Electronic simulation of the supported liquid membrane in electromembrane extraction systems: Improvement of the extraction by precise periodical reversing of the field polarity.

In order to understand the limitations of electromebrane extraction procedure better, a simple equivalent circuit has been proposed for a supported liquid membrane consisting of a resistor and a low leakage capacitor in series. To verify the equivalent circuit, it was subjected to a simulated periodical polarity changing potential and the resulting time variation of the current was compared with that of a real electromembrane extraction system. The results showed a good agreement between the simulated current patterns and those of the real ones.