Biodegradable alginate hydrogel incorporated of selenide polysaccharide to improve slow-release and selenium enrichment of vegetable.

Selenium fertilizers (Se-fertilizers) were applied to promote the growth of plant and improve the Se content in crops. However, traditional Se-fertilizers have low utilization efficiency of Se due to adsorption or leaching. Herein, Alg-g-Polyacrylamide/Se orange peel polysaccharide (AP/SeOPP) hydrogel was prepared and characterized by FT-IR, SEM, XRD and XPS.

An HDBB-based fluorescent probe for the sensitive detection of human serum albumin.

The detection of human serum albumin (HSA) in bodily fluids is of great significance in the biomedical area because HSA in bodily fluids is commonly used as a biomarker for the early diagnosis of diseases. To detect HSA, we employed HDBB, 4,4'-(hydrazine-1,2-diylidene bis(methanylylidene)) bis(3-hydroxybenzoic acid), as a fluorescent probe with a large Stokes shift. HDBB had obvious excited state intramolecular proton transfer (ESIPT) and aggregation-induced emission (AIE) features.

A novel near-infrared fluorescent probe for ultrasensitive and visual detection of mitochondrial viscosity.

The development of fluorescent probes capable of detecting abnormal changes in cellular mitochondrial viscosity is of great significance, as these changes have been connected to many diseases. In this study, the conventional tetraphenylethylene (TPE) molecule was modified to fabricate a novel near-infrared fluorescent, TTPB, which was then used to measure the mitochondrial viscosity. Due to the introduction of TPE and pyridine groups, TTPB had an AIE effect and mitochondrial targeting function.

A versatile AIE probe with mitochondria targeting for dual-channel detection of superoxide anion and viscosity.

Abnormal viscosity and excessive superoxide anion (O) levels in living cells often cause a series of biological dysfunction and oxidative damage. However, a great challenge remains in quickly and conveniently detecting the viscosity and O levels in living cells. Herein, we fabricated a versatile aggregation-induced emission (AIE) probe with mitochondria targeting, DTPB, for dual-imaging of viscosity and O level in living cells with two different channels.

Copper nanoclusters stabilized by D-penicillamine for ultrasensitive and visual detection of oxytetracycline.

Copper nanoclusters (DPA@CuNCs) with red fluorescence were successfully synthesized by a one-step method based on D-penicillamine (DPA), which acted not only as a reducing agent but also as a stabilizer. The products were characterized by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy, particle-size analysis, ultraviolet-visible spectrophotometry, and fluorescence spectrometry. When the excitation wavelength was 280 nm, DPA@CuNCs emitted bright red fluorescence at 640 nm with a fluorescence quantum yield of 5.

Aggregation-induced emission (AIE) nanoparticles based on γ-cyclodextrin and their applications in biomedicine.

Amphiphilic AIE nanoparticles (CD-TPE) were obtained by linking γ-cyclodextrin (γ-CD) and 1, 2-diphenyl-1, 2-(p-hydroxyphenyl)-ethylene (OH-TPE-OH) by an esterification reaction using hexamethylene diisocyanate (HMDI) in a one-step process. The CD-TPE was characterized by FTIR, C NMR, DSC, XRD, particle size analysis, TEM, and FL. The obtained CD-TPE had good water dispersibility and could self-assemble into AIE nanoparticles.

Adsorption behavior of copper ions using crown ether-modified konjac glucomannan.

A novel supramolecular polysaccharide composite [KGM + DB18C6] was prepared from konjac glucomannan (KGM) and dibenzo-18-crown-6 (DB18C6) using ceric ammonium nitrate as initiator. The products were characterized by FTIR, TG, DSC, UV-Vis, XRD, solid-state C NMR, and SEM. Due to the introduction of crown ether, [KGM + DB18C6] showed good adsorption performance for Cu in aqueous, and the maximum adsorption capacity was 194 mg/g under the optimal adsorption condition.

Facile fabrication of MOF(Fe)@alginate aerogel and its application for a high-performance slow-release N-fertilizer.

In this work, a novel MOF(Fe)@NaAlg aerogels composite were fabricated by a facile method of ion cross-linking, and characterized via Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetric analysis (TG), X-ray photoelectron spectroscopy (XPS) and BET surface area analysis. The MOF(Fe)@NaAlg aerogels loaded by ammonium (NH) was prepare to the slow-release fertilizer (SRF). The adsorption capacity and swelling of MOF(Fe)@NaAlg(2:10) were 29.

Analysis of volatile compounds in traditional smoke-cured bacon(CSCB) with different fiber coatings using SPME.

The volatile compounds of Chinese traditional smoke-cured bacon (CSCB) were studied using SPMS-GC/MS. There were 48 volatile compounds identified and quantified, which belonged to several classes of chemical: 1 alkane, 16 aldehydes, 5 ketones, 9 alcohols, 4 thioethers and thiols, 3 furans and 10 phenols compounds. All the volatile compounds except for alkane was responsible for CSCB characteristic flavor.