Publications by authors named "Darya O Kozlova"
Article Synopsis
- Di(het)aryldiynes react with -benzylaldimines through a [4 + 3] cycloaddition using the KOBu/DMSO system, leading to tetra(het)arylsubstituted 3-azepines with yields up to 71%.
- The reaction involves adding azaallyl anions to the diynes, resulting in prototropic isomerization and subsequent cyclization with the other triple bond.
- This process is supported by quantum-chemical analysis, confirming the proposed mechanism.
