Publications by authors named "Daria Brykczynska"

Article Synopsis
  • - The study focuses on polyoxometalates (POMs), which are promising for energy storage due to their unique electrochemical properties, but face challenges due to high solubility in common electrolytes.
  • - Researchers developed two new polyoxometalate-covalent organic frameworks (POCOFs) using a single-step process that enhances stability and performance by introducing hydroxyl groups.
  • - The best performing POCOF-1 electrodes showed impressive electrochemical metrics, including high capacitance, energy density, and excellent durability, outperforming both POCOF-2 and traditional POM electrodes.
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Geminal bis(silanes) are unique compounds with interesting properties. The most straightforward way to access them is double hydrosilylation of alkynes, which was established only recently. Previous articles about transition metal-catalysed double hydrosilylation show that terminal aryl alkynes are a challenge.

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Sulfonyl fluorides have emerged as powerful "click" electrophiles to access sulfonylated derivatives. Yet, they are relatively inert towards C-C bond forming transformations, notably under transition-metal catalysis. Here, we describe conditions under which aryl sulfonyl fluorides act as electrophiles for the Pd-catalyzed Suzuki-Miyaura cross-coupling.

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Elucidation of the structure and function of biomolecules provides us knowledge that can be transferred into the generation of new materials and eventually applications in e.g., catalysis or bioassays.

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