The rapid sulfhydrylation of chlorothalonil (CHT) in sulfur-rich vegetable matrices was observed in our previous study. However, the formation pathway, residual behavior, and toxicity of sulfhydrylated CHT remain unclear. In this study, we reveal that 4-sulfhydryl chlorothalonil (4-SH-CHT) can be formed by the reaction of CHT with HS species.
View Article and Find Full Text PDFThe migration of primary aromatic amines (PAAs) from food contact materials raises significant public health concerns. In this study, the migration levels of 26 PAAs were analyzed in 242 nylon cooking utensils using ultra-performance liquid chromatography-tandem mass spectrometry. A total of 18 PAAs were detected, of which 14 were quantified, with 4,4'-diaminodiphenylmethane (4,4'-MDA) and aniline being the most prevalent ones.
View Article and Find Full Text PDFThis study investigated the regional, seasonal, and species abundance and characteristics of microplastics (MPs) in bivalves from Qingdao, China and assessed the dietary exposure of MPs through bivalve consumption. The average abundance was 1.17 ± 1.
View Article and Find Full Text PDFNovel techniques and methodologies are being developed to advance food safety risk assessment into the next-generation. Considering the shortcomings of traditional animal testing, new approach methodologies (NAMs) will be the main tools for the next-generation risk assessment (NGRA), using non-animal methodologies such as and approaches. The United States Environmental Protection Agency and the European Food Safety Authority have established work plans to encourage the development and application of NAMs in NGRA.
View Article and Find Full Text PDFFood Addit Contam Part B Surveill
September 2023
Ceramic products are among the most frequently used food contact materials. Health risks associated with ceramic tableware usually arise from the migration of heavy metals. In this study, 767 pieces of ceramic tableware of different shapes and types were collected across China, and the migration levels of 18 elements were determined using inductively coupled plasma mass spectrometry.
View Article and Find Full Text PDFFood Chem Toxicol
March 2023
Caffeine is a kind of psychostimulant that naturally exist in foods. The benefits and risks of caffeine depend on the dose. Moreover, the intake of caffeine from dietary sources in China has seldom been assessed.
View Article and Find Full Text PDFInt J Environ Res Public Health
November 2022
Rare earth elements (REEs) are widely found in foods. A high intake of REEs may have associations with adverse effects on human health. This study aimed to investigate the concentrations of REEs in foods in China and to assess the risk of dietary REEs exposure in the Chinese population.
View Article and Find Full Text PDFThis paper presented an innovative method for fabrication of a porous AlO/CaAlO ceramic membrane by combining emulsion method, cement curing and tape-casting technologies. The ceramic membrane featured a smooth surface and a porous internal structure. By adjusting the oil-water volume ratio from 1:1 to 4:1, the porosity of the samples increases from 45.
View Article and Find Full Text PDFFood Addit Contam Part A Chem Anal Control Expo Risk Assess
December 2021
Food Addit Contam Part A Chem Anal Control Expo Risk Assess
December 2021
The release of metal elements from stainless-steel products in contact with food may endanger human health. To protect human health, different countries or international organisations have formulated corresponding regulations or technical guidelines. Limits for only five metal elements are stipulated in the China National Food Safety Standard (GB 4806.
View Article and Find Full Text PDFThe escalating concerns regarding air pollution problems surrounding port cities have attracted much research attention. The Port of Shenzhen is one of the busiest container ports worldwide, only third to Shanghai and Singapore globally. However, 70% of the freight transportation demand is satisfied via on-road trucks, leading to serious traffic congestion, road accidents and air pollution issues in the city of Shenzhen.
View Article and Find Full Text PDFFood Addit Contam Part A Chem Anal Control Expo Risk Assess
September 2021
Recently, mineral oil hydrocarbons (MOH) in various foods have raised significant concern, especially for infants and young children due to their potential adverse health effects. Two fractions can be distinguished by certain analytical techniques, mineral oil saturated hydrocarbons (MOSH) and mineral oil aromatic hydrocarbons (MOAH). The toxicological profile of MOSH and MOAH differs greatly.
View Article and Find Full Text PDFEnzyme Microb Technol
April 2021
Alcohol oxidase (AOx) from P. pastoris has potential applications in the production of carbonyl compounds and for the detection and quantification of alcohols. However, AOx's poor stability and low activity have hindered its practical application.
View Article and Find Full Text PDFMost studies dealing with monitoring the dynamics of biofilm formation use microbial suspensions at high concentrations. These conditions do not always represent food or water distribution systems. A continuous flow system capable of controlling the concentration of the microbial suspension stream from 10 to 10 CFU ml is reported.
View Article and Find Full Text PDFWe report the effects of high hydrostatic pressure (HHP), immobilization in electrochemically generated poly-o-phenylenediamine nano-films, and reticulation with glutaraldehyde on the thermal stability of glucose oxidase (GOx). The pseudo-first-order rate constant of inactivation of immobilized GOx inactivated at 70 °C and atmospheric pressure was 20.6 times smaller than that of GOx in solution under the same conditions.
View Article and Find Full Text PDFIn this work, we examined the performance of 2D titanate nanosheets for dye adsorption. Their adsorption capacity for methylene blue (MB) is up to 3937 mg g, which is more than 10 times higher than active carbon and occupies the highest place among all the reports.
View Article and Find Full Text PDFMaterials (Basel)
May 2018
A large-scale production of necklace-like SiC/SiO₂ heterojunctions was obtained by a molten salt-mediated chemical vapor reaction technique without a metallic catalyst or flowing gas. The effect of the firing temperature on the evolution of the phase composition, microstructure, and morphology of the SiC/SiO₂ heterojunctions was studied. The necklace-like SiC/SiO₂ nanochains, several centimeters in length, were composed of SiC/SiO₂ core-shell chains and amorphous SiO₂ beans.
View Article and Find Full Text PDFFunctionalized porous carbon materials with hierarchical structure and developed porosity coming from natural and renewable biomass have been attracting tremendous attention recently. In this work, we present a facile and scalable method to synthesize MnO2 loaded carbonaceous aerogel (MnO2@CA) composites via the hydrothermal carbonaceous (HTC) process. We employ two reaction systems of the mixed metal ion precursors to study the optimal selective adsorption and further reaction of MnO2 precursor on CA.
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