Formation of marine oil snow by soot particles generated from burning of oils.

This study aims to investigate the interactions between marine oil snow (MOS) formation and soot particles derived from two distinct oils: condensate and heavy oil. Experimental findings demonstrate that the properties of oil droplets and soot particles play a key role in MOS formation. Peak MOS formation is observed within the initial days for condensate, while for heavy oil, peak formation occurs at a later stage.

A review of the pollution signatures of polycyclic aromatic hydrocarbons in the sediments of the East China Sea.

Marine sediments serve as crucial reservoirs for polycyclic aromatic hydrocarbons (PAHs), and their PAH signatures offer valuable historical pollution records. This article provides a comprehensive review of the pollution status of 16 priority PAHs in more than 1000 sediments from the East China Sea (ECS). It focuses on the PAH sources, spatiotemporal distributions, driving factors, and ecological risks, with information derived from peer-reviewed papers published between 2003 and 2023.

Carbon storage estimation and strategy optimization under low carbon objectives for urban attached green spaces.

In the context of rapid urbanization, scarce land resources have highlighted the importance of attached green spaces (AGS), which have received limited attention despite their critical importance in the urban carbon cycle. Analyzing the differences in carbon storage of different AGS types and proposing different optimization strategies can provide a reference for urban managers to scientifically enhance the carbon sinks of greenfield. This study estimated the carbon storage of AGS in central Shanghai using a series of detailed field survey data and remote sensing data.

Systematic literature review of solar-powered landfill leachate sanitation: Challenges and research directions over the past decade.

Researchers have documented the negative effects of refractory chemicals and emergent pollutants in landfill leachate (LL) that cannot be degraded using conventional methods. The propagation, invasion, and deleterious effects of several LL hazards affect aquatic species, the environment, and food outlets, causing significant safety issues. These include cancer risks, chronic exposure, and reproductive consequences.

Chemical signatures of polycyclic aromatic hydrocarbons in the emissions from in situ oil burns.

This study characterized the parent and alkylated polycyclic aromatic hydrocarbons (PAHs) in gaseous and particulate emissions from the in situ burning (ISB) of oils. The experimental results indicate that the burning of the heavy oil produced the most PAH emissions because of its longest burning time. In addition, the parent PAHs mainly exist in the particulate phase, while alkylated PAHs mostly accumulate in the gaseous phase.

Surface Modification of TiO Nanotubes Prepared by Porous Titanium Anodization via Hydrothermal Reaction: A Method for Synthesis High-Efficiency Adsorbents of Recovering Sr Ions.

The recycling of strontium ions (Sr) from sea water has been well known for its good cost-effectiveness and environment friendliness. Herein, we modified the surface of TiO nanotubes (TNTs) prepared by porous titanium anodization via hydrothermal (HT) reaction and synthesized a highly efficient adsorbent for the repeated recycling of Sr. TNTs with a high specific surface area were manufactured on porous titanium by internal anodic oxidation.

The fingerprint stability of the biomarker hopanes and steranes in soot emissions from in-situ burning of oil.

The behavior of emissions is an important concern of in-situ burning (ISB) of spilled oils. In particular, the heavy soot originated from ISB can negatively impact the atmospheric environment. To track the behavior of ISB soot, the conservative biomarkers, such as hopanes and steranes, can be potentially used.

Electrochemical degradation performance and mechanism of dibutyl phthalate with hydrophobic PbO electrode.

A polytetrafluoroethylene (PTFE) doped PbO anode with a highly hydrophobicity was fabricated by electrodeposition method. In this process, vertically aligned TiO nanotubes (TiONTs) are formed by the anodic oxidation of Ti plates as an intermediate layer for PbO electrodeposition. The characterization of the electrodes indicated that PTFE was successfully introduced to the electrode surface, the TiONTs were completely covered with β-PbO particles and gave it a large surface area, which also limited the growth of its crystal particles.

Application of a fugacity model to estimate emissions and environmental fate of ship stack PAHs in Shanghai, China.

The understandings of environmental activities and regional inventory of ship stack PAHs are very limited in Shanghai due, in part, to the lack of source-segregated analysis. To address this, measured PAHs in organic film on ship surfaces were employed to reconstruct concentrations in various compartments through a fugacity model to investigate the level, transport, fate and annual emission of ship stack PAHs in Shanghai. The results revealed that ship stack PAHs results in 11.

Polycyclic aromatic hydrocarbon contamination along roads based on levels on vehicle window films.

Vehicular emissions are known to be major contributors of airborne polycyclic aromatic hydrocarbons (PAHs) in cities. In order to assess the long-term contamination of PAHs along roads, we collected organic films from vehicle windows (26 private cars and 4 buses, in Shanghai, China) and used mathematical models to convert the film-bound PAH concentrations to the airborne PAH concentrations. The field measurements of airborne PAHs revealed that the partitioning and Level III fugacity model was suitable to estimate the airborne concentrations of high and low volatile PAHs (expect for naphthalene), respectively.

Polycyclic aromatic hydrocarbon contaminations along shipping lanes and implications of seafarer exposure: Based on PAHs in ship surface films and a film-air-water fugacity model.

Polycyclic aromatic hydrocarbons (PAHs) are one of the most toxic compounds in ship tailpipe exhausts. The long-term contamination of PAHs along shipping lanes and ports is difficult to assess using conventional methods such as AIS-EFs-data based (AIS, Automatic identification system; EFs, emission factors) or field sampling methods. To address this, we collected the organic films on ship surfaces and used a modified film-air-water fugacity model to convert the film-bound concentrations to the airborne (gaseous plus particulate) concentrations.

Emissions of intermediate volatility organic compound from waste cooking oil biodiesel and marine gas oil on a ship auxiliary engine.

Ship auxiliary engines contribute large amounts of air pollutants when at berth. Biodiesel, including that from waste cooking oil (WCO), can favor a reduction in the emission of primary pollutant when used with internal combustion engines. This study investigated the emissions of gaseous intermediate-volatile organic compounds (IVOCs) between WCO biodiesel and marine gas oil (MGO) to further understand the differences in secondary organic aerosol (SOA) production of exhausts.

A scientometric visualization analysis for global toxicology and pharmacology research of natural products from 1962 to 2018.

Background: A growing number of studies have been focused on the medicinal potential of natural products since 1962, while few scholars have analyzed the existing documents comprehensively.

Purpose: Aiming to visualize the researches on toxicology and pharmacology of natural products (TPNP) published between 1962 and 2018, as well as to reveal their spatiotemporal patterns, a scientometric analysis with 3210 relevant documents collected from Web of Science was conducted in this study.

Results: The most prominent contributors of TPNP research are mainly from the USA, China, Brazil, India and Germany.

Emission of intermediate volatility organic compounds from a ship main engine burning heavy fuel oil.

Intermediate volatility organic compounds (IVOCs) are crucial precursors of secondary organic aerosol (SOA). In this study, gaseous IVOCs emitted from a ship main engine burning heavy fuel oil (HFO) were investigated on a test bench, which could simulate the real-world operations and emissions of ocean-going ships. The chemical compositions, emission factors (EFs) and volatility distributions of IVOC emissions were investigated.

Growth orientation mechanism of TiO nanotubes fabricated by anodization.

TiO nanotubes (TNTs) fabricated by anodization have been extensively researched in recent years. However, the mechanism that controls the growth orientation of anodic TNTs is still not clear. Here, we firstly examine their growth orientation systematically.

Gas/particle partitioning, particle-size distribution of atmospheric polybrominated diphenyl ethers in southeast Shanghai rural area and size-resolved predicting model.

A size-segregated gas/particle partitioning coefficient K was proposed and evaluated in the predicting models on the basis of atmospheric polybrominated diphenyl ether (PBDE) field data comparing with the bulk coefficient K. Results revealed that the characteristics of atmospheric PBDEs in southeast Shanghai rural area were generally consistent with previous investigations, suggesting that this investigation was representative to the present pollution status of atmospheric PBDEs. K was generally greater than bulk K, indicating an overestimate of TSP (the mass concentration of total suspended particles) in the expression of bulk K.

Composition and influencing factors of bacterial communities in ballast tank sediments: Implications for ballast water and sediment management.

This study aims to reveal the composition and influencing factors of bacterial communities in ballast tank sediments. Nine samples were collected and their 16S rRNA gene sequences were analyzed by high-throughput sequencing. The analysis results showed the Shannon index in ballast tank sediments was in the range of 5.

Atmospheric bulk deposition of polycyclic aromatic hydrocarbons in Shanghai: Temporal and spatial variation, and global comparison.

Atmospheric deposition leads to accumulation of atmospheric polycyclic aromatic hydrocarbons (PAHs) on urban surfaces and topsoils. To capture the inherent variability of atmospheric deposition of PAHs in Shanghai's urban agglomeration, 85 atmospheric bulk deposition samples and 7 surface soil samples were collected from seven sampling locations during 2012-2014. Total fluxes of 17 PAHs were 587-32,300 ng m day, with a geometric mean of 2600 ng m day.

Occurrences, composition profiles and source identifications of polycyclic aromatic hydrocarbons (PAHs), polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) in ship ballast sediments.

The aim of this study was to investigate the levels of persistent organic pollutants (POPs) including polycyclic aromatic hydrocarbons (PAHs), polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) in ship ballast sediments. The ballast sediment samples were collected from six merchant ships docked in 2015 in Jiangyin City, China. Ballast sediments represent a potential vector for the transport of POPs and invasive species between marine environments.

Pollution characteristics and ecological risk of heavy metals in ballast tank sediment.

This study was conducted to illustrate the contents and potential ecological risk of heavy metals in ballast tank sediment. Ballast sediment samples were collected from six ships during their stay in shipyard, and the heavy metals were determined by inductive coupled plasma emission spectrometer. Results showed that high concentrations of heavy metals were detected in all six sediment samples following the order: Zn > Cu > Pb > Cr > As > Cd > Hg.

Self-powered denitration of landfill leachate through ammonia/nitrate coupled redox fuel cell reactor.

In order to explore the feasibility of energy-free denitrifying N-rich wastewater, a self-powered device was uniquely assembled, in which ammonia/nitrate coupled redox fuel cell (CRFC) reactor was served as removing nitrogen and harvesting electric energy simultaneously. Ammonia is oxidized at anodic compartment and nitrate is reduced at cathodic compartment spontaneously by electrocatalysis. In 7.

Inactivation of Heterosigma akashiwo in ballast water by circular orifice plate-generated hydrodynamic cavitation.

The discharge of alien ballast water is a well-known, major reason for marine species invasion. Here, circular orifice plate-generated hydrodynamic cavitation was used to inactivate Heterosigma akashiwo in ballast water. In comparison with single- and multihole orifice plates, the conical-hole orifice plate yielded the highest inactivation percentage, 51.

Laboratory study of the particle-size distribution of Decabromodiphenyl ether (BDE-209) in ambient air.

Laboratory measurements for particle-size distribution of Decabromodiphenyl ether (BDE-209) were performed in a 0.5 m(3) sealed room at 25 °C. BDE-209 was manually bounded to ambient particles.

Application of immobilized TiO2 photocatalysis to improve the inactivation of Heterosigma akashiwo in ballast water by intense pulsed light.

Ballast water exotic discharge has been identified as a leading vector for marine species invasion. Here immobilized TiO2 photocatalysis is introduced to improve the performance of intense pulsed light. For intense pulsed light/TiO2 photocatalysis, a typical inactivation of 99.

Inactivation of microalgae in ballast water with pulse intense light treatment.

The exotic emission of ballast water has threatened the coastal ecological environment and people's health in many countries. This paper firstly introduces pulse intense light to treat ballast water. 99.