Publications by authors named "Danilo Manzani"

A reversible optoelectronic nose is presented consisting of ten acid-base indicators incorporated into a starch-based film, covering a wide pH range. The starch substrate is odorless, biocompatible, flexible, and exhibits high tensile resistance. This optical artificial olfaction system was used to detect the early stages of food decomposition by exposing it to the volatile compounds produced during the spoialge process of three food products (beef, chicken, and pork).

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Tellurite glasses have garnered considerable interest as optical host materials due to their advantageous properties, including low processing temperature, high resistance to corrosion and crystallization, and excellent solubility for rare earth ions. However, their applicability in the infrared (IR) region is limited by the absorption of species with distinct vibrations. The incorporation of fluorides has emerged as a promising approach to reduce hydroxyl (OH) absorption during the precursor melting process.

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The unique tunable properties of glasses make them versatile materials for developing numerous state-of-the-art optical technologies. To design new optical glasses with tailored properties, an extensive understanding of the intricate correlation between their chemical composition and physical properties is mandatory. By harnessing this knowledge, the full potential of vitreous matrices can be unlocked, driving advancements in the field of optical sensors.

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While phosphotellurite glasses have superior properties over SiO-based glasses for many applications in optoelectronics and photonic devices, their high hydroxyl content limits their use in the mid-infrared range. This drawback can be overcome by fluoride addition to the formulation. In this work, we report the preparation, optical, and structural characterization of new glasses in the ternary system TeO-NaF-NaPO having the compositions 0.

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Glass and glass-ceramics containing nanocrystals of BiTeO cubic phase co-doped with Er and Yb were prepared by heat treatment of the precursor tellurite glass and investigated for optical applications. Lanthanide doped tellurite glass and glass-ceramics have been extensively investigated because of their optical and photoluminescence performance for technological photonic applications. Er and Er/Yb doped TeO-GeO-KO-BiO tellurite glass compositions were prepared by the conventional melt-quenching method.

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This study is focused on the development of a nanodevice for loading and release of 5-Fluorouracil (5-FU) with a view to improving its therapeutic efficiency, using as strategy the fabrication of a nanoconjugate through drug anchorage on the surface of carbon quantum dots (CQD). Several physicochemical and analytical techniques were employed to obtain information about materials morphology, structure, and optical properties. The results indicated that the interactions between both entities resulted in good physicochemical properties and photostability.

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Phosphotellurite based glasses have interesting features such as low characteristic temperatures, high glass forming ability, high thermal stability against crystallization and a broad transparency window from ultraviolet (UV) to near-infrared (NIR), which makes them promising materials for photonic applications. In this work, phosphotellurite binary glasses, having a composition (100 - x)TeO2 - xBa(PO3)2 with x varying from 1 to 20 mol%, were synthesized by the conventional melt-quenching method in covered gold crucibles under air. Optical, physical and structural properties of the new glass samples were investigated by differential scanning calorimetry, X-ray diffraction, Raman spectroscopy, transmission electron microscopy, linear optical absorption from UV to NIR, IR transmittance, and optical limiting experiments.

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The determination of temperature is essential in many applications in the biomedical, technological, and industrial fields. Optical thermometry appears to be an excellent alternative for conventional electric temperature sensors because it is a non-contact method that offers a fast response, electromagnetic passivity, and high temperature sensitivity. In this paper, we propose an optical thermometer probe comprising an Er/Yb co-doped tellurite glass attached to the tip of an optical fibre and optically coupled to a laser source and a portable USB spectrometer.

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Glasses in the ternary system (70 - x)NaPO(3)-30WO(3)-xBi(2)O(3), with x = 0-30 mol %, were prepared by the conventional melt-quenching technique. X-ray diffraction (XRD) measurements were performed to confirm the noncrystalline nature of the samples. The influence of the Bi(2)O(3) on the thermal, structural, and optical properties was investigated.

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