Enhanced Heterogeneous Fenton Degradation of Organic Dyes by Bimetallic Zirconia-Based Catalysts.

The qualitative impact of pollutants on water quality is mainly related to their nature and their concentration, but in any case, they determine a strong impact on the involved ecosystems. In particular, refractory organic compounds represent a critical challenge, and several degradation processes have been studied and developed for their removal. Among them, heterogeneous Fenton treatment is a promising technology for wastewater and liquid waste remediation.

How to choose the best tertiary treatment for pulp and paper wastewater? Life cycle assessment and economic analysis as guidance tools.

Pulp and paper wastewater (P&P WW) often requires tertiary treatment to remove refractory compounds not eliminated by conventional biological treatment, ensuring compliance with high-quality effluent discharge or reuse standards. This study employs a life cycle assessment (LCA) methodology to compare alternative tertiary treatment technologies for P&P WW and rank them accordingly. The evaluated technologies in the scenarios include inorganic (S1) and organic (S2) coagulation-flocculation, ozonation (O) (S3), O+granular activated carbon (GAC) (S4), and ultrafiltration (UF)+reverse osmosis (RO) (S5).

Wastewater fertigation in agriculture: Issues and opportunities for improved water management and circular economy.

Water shortages are an issue of growing worldwide concern. Irrigated agriculture accounts for about 70% of total freshwater withdrawals globally, therefore alternatives to use of conventional sources need to be investigated. This paper critically reviews the application of treated wastewater for agricultural fertigation (i.

Alternative seagrass wrack management practices in the circular bioeconomy framework: A life cycle assessment approach.

Despite providing important ecological functions, seagrass accumulation causes environmental and economic issues, including eutrophication and tourism reduction. Nowadays, seagrass wrack is commonly removed from the beaches and landfilled, which is considered the least desirable practice according to the European Union (EU) Waste Framework Directive. In this study, different management strategies for seagrass valorisation, including anaerobic digestion (AD), composting and ecological restoration, were considered using a life cycle assessment (LCA) perspective.

Respirometry tests in wastewater treatment: Why and how? A critical review.

Respirometry tests are a widely employed method in wastewater treatment field to characterize wastewater streams, assess toxic/inhibitory effects to the biomass, calibrate mathematical models. Respirometry can allow to fractionize the chemical oxygen demand (COD) in biodegradable and inert fractions, but also provide information related to biomass kinetics and stoichiometry through standardized laboratory techniques. Considering the increasing number of emerging contaminants detected in wastewater effluents, such as pharmaceuticals, personal care products and pesticides, respirometry can be a useful tool to promptly assess any toxic or inhibitory effect in wastewater treatment plants (WWTPs) operations.

Combined ultrasound-ozone treatment for reutilization of primary effluent-a preliminary study.

The present work is a preliminary study on the potential of low-frequency ultrasound irradiation coupled with O process for the disinfection of a primary effluent from a municipal wastewater treatment plant preserving nutrient levels (in particular nitrogen and phosphorous), for its possible reuse in civil, industrial, and agricultural sectors. The treated water could be reused, after appropriate dilution, contributing to the circular economy perspective and reducing the need for both chemical fertilizer addition and freshwater supply. The effect of different specific ultrasonic energies and ozone doses was assessed on a bench-top system, composed of an ultrasonic reactor and a semi-batch ozonation vessel.

Automated calibration of the EPA-SWMM model for a small suburban catchment using PEST: a case study.

Rainfall-runoff models must be calibrated and validated before they can be used for urban stormwater management. Manual calibration is very difficult and time-consuming due to the large number of model parameters that must be estimated concurrently. Automatic calibration offers as a promising alternative, ideally supporting a user-independent and time-efficient approach to model parameters estimation.

Up-Flow Anaerobic Sludge Blanket (UASB) Technology for Energy Recovery: A Review on State-of-the-Art and Recent Technological Advances.

Up-flow anaerobic sludge blanket (UASB) reactor belongs to high-rate systems, able to perform anaerobic reaction at reduced hydraulic retention time, if compared to traditional digesters. In this review, the most recent advances in UASB reactor applications are critically summarized and discussed, with outline on the most critical aspects for further possible future developments. Beside traditional anaerobic treatment of soluble and biodegradable substrates, research is actually focusing on the treatment of refractory and slowly degradable matrices, thanks to an improved understanding of microbial community composition and reactor hydrodynamics, together with utilization of powerful modeling tools.

Techno-economic feasibility of anaerobic digestion of cheese whey in small Italian dairies and effect of ultrasound pre-treatment on methane yield.

In Friuli-Venezia Giulia plain (North-East of Italy), a significant number of small diaries is present; this study was aimed at evaluating technical and economic feasibility of diffused anaerobic digestion implementation at dairy level. Different kinds of cheese whey were characterized, and biochemical methane potential tests were executed. Good methane yields (up to 437.

(Eco)toxicological maps: A new risk assessment method integrating traditional and in silico tools and its application in the Ledra River (Italy).

Contaminants giving rise to emerging concern like pharmaceuticals, personal care products, pesticides and Endocrine Disrupting Chemicals (EDCs) have been detected in wastewaters, as reported in the literature, but little is known about their (eco)toxicological effects and consequent human health impact. The present study aimed at overcoming this lack of information through the use of in silico methods integrated with traditional toxicological risk analysis. This is part of a pilot project involving the management of wastewater treatment plants in the Ledra River basin (Italy).

Pilot plant experience on anaerobic codigestion of source selected OFMSW and sewage sludge.

Anaerobic codigestion of source selected organic fraction of municipal solid waste (SS-OFMSW) and sewage sludge may be one of the most viable solutions to optimize oversized digesters efficiency in wastewater treatment plants. Based on results of BMP tests obtained for sewage sludge and SS-OFMSW, pilot plant tests were carried out by 3.4 m(3) CSTR reactor at mesophilic temperature.

Rheology measurements for online monitoring of solids in activated sludge reactors of municipal wastewater treatment plant.

Rheological behaviour of recycled sludge from a secondary clarifier of a municipal wastewater treatment plant was studied by using the rate controlled coaxial cylinder viscometer Rotovisko-Haake 20, system M5-osc., measuring device NV. The tests (hysteresis cycles) were performed under continuous flow conditions and following an ad hoc measurement protocol.

BMP tests of source selected OFMSW to evaluate anaerobic codigestion with sewage sludge.

The aim of this study is to characterize different types of source selected organic fraction of municipal solid waste (SS-OFMSW) in order to optimize the upgrade of a sewage sludge anaerobic digestion unit by codigestion. Various SS-OFMSW samples were collected from canteens, supermarkets, restaurants, households, fruit-vegetable markets and bakery shops. The substrates characterization was carried out getting traditional chemical-physical parameters, performing elemental analysis and measuring fundamental anaerobic digestion macromolecular compounds such as carbohydrates, proteins, lipids and volatile fatty acids.

Land application of aerobic sewage sludge does not impair methane oxidation rates of soils.

The aim of this study was to measure and compare methane oxidation rates of arable and grassland soils that received 7.5t ha⁻¹ y⁻¹ of noncontaminated aerobically treated sewage sludge for ten years. Arable soils showed generally lower methane oxidation rates (from 6 to 15∗10⁻³ h⁻¹) than grassland soils (from 26 to 33∗10³ h⁻¹).

Salt-assisted thermal desorption of mercury from contaminated dredging sludge.

In this study, we tested a new procedure for the decontamination of mercury-polluted dredging sludge (Marano-Grado Lagoon, northeastern Italy) based on cationic exchange associated with thermal desorption at a low temperature. Four mercury-polluted sludge slurries were treated using thermal desorption at 393 K for 2h. Three different salts, NaCl (sodium chloride), (CH(3))(4)NCl (tetramethylammonium chloride) and (C(4)H(9))(4)NCl (tetrabutylammonium chloride) were used as exchangers.

Bench-scale tests on ultrasound-assisted acid washing and thermal desorption of mercury from dredging sludge and other solid matrices.

A series of ultrasonic assisted acid washing and thermal desorption tests were performed on sludge and other solid matrices with the aim to assay these removal technologies and to determine if the application of low frequency ultrasound was effective to enhance mercury removal. Unpolluted dredging sludge, 820 K calcinated dredging sludge, silica and alumina were characterized, polluted with a known concentration of mercury and treated both by acid washing and thermal desorption with and without low frequency ultrasound application. The acid washing was carried out by a 4% HNO(3) acid solution and the thermal desorption was performed in a 370-620K range.

Evaluation of chlorinated by-products in drinking waters of Central Friuli (Italy).

Drinkable water supplied by aqueducts undergoes preliminar potabilization which, in Italy, is mainly accomplished by chlorine addition. The bactericidal action involved in this process is always accompanied by chlorination and oxidation of organic species (mainly humic and fulvic acids) naturally present in treated waters, so that many disinfection by-products (DBPs) are formed, such as trihalomethanes (THMs) and halo-acetic acids (HAA), which can represent a chemical risk for public health. The aim of this study was the monitoring of DBPs in drinking water disinfected by chlorination, supplied by four different aqueducts of Central Friuli (Italy).

Analysis of metals and EOX in sludge from municipal wastewater treatment plants: a case study.

The monitoring of extractable organic halogen (EOX) and heavy metal contents in sludge coming from 10 different municipal wastewater treatment plants (MWWTP) located in Friuli Venezia Giulia (Italy) is reported. In this work, sludge samples drawn from sludge treatment units have been digested and analyzed by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) for metal evaluation. Samples were also extracted and analyzed by microcoulometric titrations, following modified DIN 38414 T17 standard, for EOX analysis.