Heterogeneous deacetylation reaction of chitin under low-frequency ultrasonic irradiation.

Low-frequency ultrasonic irradiation was employed as a low cost technique for chitin's deacetylation at a relatively low-temperature range (below 70 °C) and a short reaction times (up to 120 min). Eley-Rideal mechanism and the power-law model were carried out to describe the mechanism of the reaction. The results indicated that the produced chitosan deacetylation degree (DD) was up to 87.

Nanofluid to Nanocomposite Film: Chitosan and Cellulose-Based Edible Packaging.

Chitosan (CH)-based materials are compatible to form biocomposite film for food packaging applications. In order to enhance water resistance and mechanical properties, cellulose can be introduced to the chitosan-based film. In this work, we evaluate the morphology and water resistance of films prepared from chitosan and cellulose in their nanoscale form and study the phenomena underlying the film formation.

Cellulose Nanocrystals to Improve Stability and Functional Properties of Emulsified Film Based on Chitosan Nanoparticles and Beeswax.

The framework of this work was to develop an emulsion-based edible film based on a chitosan nanoparticle matrix with cellulose nanocrystals (CNCs) as a stabilizer and reinforcement filler. The chitosan nanoparticles were synthesized based on ionic cross-linking with sodium tripolyphosphate and glycerol as a plasticizer. The emulsified film was prepared through a combination system of Pickering emulsification and water evaporation.

Ultrasonic Irradiation Coupled with Microwave Treatment for Eco-friendly Process of Isolating Bacterial Cellulose Nanocrystals.

The isolation of crystalline regions from fibers cellulose via the hydrolysis route generally requires corrosive chemicals, high-energy demands, and long reaction times, resulting in high economic costs and environmental impact. From this basis, this work seeks to develop environment-friendly processes for the production of Bacterial Cellulose Nanocrystals (BC-NC). To overcome the aforementioned issues, this study proposes a fast, highly-efficient and eco-friendly method for the isolation of cellulose nanocrystals from Bacterial Cellulose, BC.

Mixed O/W emulsions stabilized by solid particles: a model system for controlled mass transfer triggered by surfactant addition.

This article deals with a model mixed oil-in-water (O/W) emulsion system developed to study the effect of surfactants on mass transfer between dispersed oil droplets of different composition. In this purpose, our goal was to formulate O/W emulsions without any surface active agents as stabilizer, which was achieved by replacing surfactants by a mixture of hydrophilic/hydrophobic silica particles. Then, to study the specific role of surfactants in the oil transfer process, different types and concentrations of surfactants were added to the mixed emulsion after its preparation.