Publications by authors named "Daniel T Gschwind"

Differently substituted phenyl isonitriles (with C-H bonds in ortho-position) and naphthyl isonitriles were reacted with the cyclic biradical [⋅P(μ-N-Ter) P⋅] (1). Insertion of the isonitrile formed a cyclic five-membered biradical [⋅P(NTer) C(R)P⋅] (2R, R=phenyl, naphthyl) in the first step, followed by C-H activation at the aryl substituent, resulting in novel azaphospholes (5R), which could be isolated and fully characterized. The formation of the azaphospholes can be prevented by the addition of a second equivalent of isonitrile, which causes the blocking of the radical centers in 2R by adduct formation (3R).

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