A Trinuclear High-Spin Iron(III) Complex with a Geometrically Frustrated Spin Ground State Featuring Negligible Magnetic Anisotropy and Antisymmetric Exchange.

The trinuclear high-spin iron(III) complex [FeCl(saltag)(py)]ClO {Hsaltag = 1,2,3-tris[(5-bromo-salicylidene)amino]guanidine} was synthesized and characterized by several experimental and theoretical methods. The iron(III) complex exhibits molecular 3-fold symmetry imposed by the rigid ligand backbone and crystallizes in trigonal space group 3̅ with the complex cation lying on a crystallographic axis. The high-spin states ( = /) of the individual iron(III) ions were determined by Mößbauer spectroscopy and confirmed by CASSCF/CASPT2 ab initio calculations.

Opto-Spintronics: Photoisomerization-Induced Spin State Switching at 300 K in Photochrome Cobalt-Dioxolene Thin Films.

Controllable quantum systems are under active investigation for quantum computing, secure information processing, and nonvolatile memory. The optical manipulation of spin quantum states provides an important strategy for quantum control with both temporal and spatial resolution. Challenges in increasing the lifetime of photoinduced magnetic states at T > 200 K have hindered progress toward utilizing photomagnetic materials in quantum device architectures.

Modeling Spin Interactions in a Triangular Cobalt(II) Complex with Triaminoguanidine Ligand Framework: Synthesis, Structure, and Magnetic Properties.

The new tritopic triaminoguanidine-based ligand 1,2,3-tris[(pyridine-2-ylmethylidene)amino]guanidine (Hpytag) was synthesized. The reaction of a mixture of cobalt(II) chloride and cobalt(II) perchlorate with the ligand Hpytag in pyridine solution leads to the formation of the trinuclear cobalt(II) complex [Co(pytag)(py)Cl]ClO. Three octahedrally coordinated high-spin cobalt(II) ions are linked through the bridging triaminoguanidine backbone of the ligand leading to an almost equilateral triangular arrangement.

A spin-frustrated trinuclear copper complex based on triaminoguanidine with an energetically well-separated degenerate ground state.

We present the synthesis and crystal structure of the trinuclear copper complex [Cu3(saltag)(bpy)3]ClO4·3DMF [H5saltag = tris(2-hydroxybenzylidene)triaminoguanidine; bpy = 2,2'-bipyridine]. The complex crystallizes in the trigonal space group R3̅, with all copper ions being crystallographically equivalent. Analysis of the temperature dependence of the magnetic susceptibility shows that the triaminoguanidine ligand mediates very strong antiferromagnetic interactions (JCuCu = -324 cm(-1)).