Human exposure to organochlorine pesticides in vegetables from major cities in south-south Nigeria.

Contamination of vegetables with organochlorine pesticides (OCPs) during cultivation could affect their nutritional value and also results in adverse health effects to consumers. Thus, this study evaluates human exposure to OCPs in vegetables from major cities in south-south Nigeria. A total of eighty vegetables consisting of Vernonia amygdalina, Telfairia occidentalis, Desmodium intortum cv and Talinum triangulare obtained from four major cities (Warri, Benin, Yenagoa and Port-Harcourt) in south-south Nigeria were analysed for OCPs using a gas chromatograph coupled with a mass selective detector.

Comparative time-based intermediates study of ozone oxidation of 4-chloro- and 4-nitrophenols followed by LCMS-TOF.

Greater insights on the degradation pathways and intermediates formed during the oxidation of organics can be achieved by more suitable and compatible instrumentation. In our research, we sought to explore the relative advantages of the liquid chromatography coupled to a time of flight mass spectrometer (LCMS-TOF) technique for the comparative time-based degradation intermediates and pathways of 4-chlorophenol (4CP) and 4-nitrophenol (4NP). The ozonation of the analytes solution (100 mL of 2 x 10 M) was done in a sintered glass reactor, with an ozone dose of 0.