Electron effect regulation: A study on the influence of electron-donating and withdrawing group modification on the performance of metal-coordinated catalysts for electrochemical carbon dioxide reduction.

Electron effect regulation is a crucial factor influencing the activity and selectivity of Cu-based coordination compound catalysts in the electrochemical carbon dioxide reduction reaction (CORR). Despite significant progress, the structure-activity relationship and the underlying regulatory mechanisms warrant further in-depth investigation. In this study, three types of Cu-[ONNO] tetradentate coordination molecular catalysts with varying electron densities, namely Cu-NO, methoxy-modified Cu-NO (Cu-EDG-NO), and nitro-modified Cu-NO (Cu-EWG-NO), were prepared using a substituent regulation strategy.

Transparent, Flexible, Responsive Switching "Delayed" Amphiphilic Coatings Designed on the Basis of the Full-Cycle Antifouling Strategy.

Marine fouling on the surface of ships and equipment not only creates problems of enhanced resistance to navigation and increased energy consumption but also leads to unclear vision and inaccurate data collection. Antifouling coatings to resist fouling are effective, but it is difficult to achieve long-lasting fouling protection with a single interface state. Switching the status of the interface by intelligent response is a reasonable way to achieve full-cycle efficient antifouling.

Advanced MXene-based materials for efficient extraction of uranium from seawater and wastewater.

In order to realize the low-carbon development policy, the large-scale development and utilization of nuclear energy is very essential. Uranium is the key resource for nuclear industry. The extracting and recycling uranium from seawater and nuclear wastewater is necessary for secure uranium reserves, ensure energy security, control pollution and protect the environment.

Self-healing and corrosion-sensing multifunctional coatings containing pH-sensitive TiO-based composites.

Polyelectrolyte-encapsulated nanocontainers can effectively respond to changes of pH and thus control the on-demand release of corrosion inhibitors. A pH-responsive release system (Phen-Tpp@MTNs-PDDA) was developed based on the cationic polyelectrolyte poly dimethyl diallyl ammonium chloride (PDDA) encapsulated mesoporous TiO nanocontainers (MTNs) loaded with 1,10-phenanthroline (Phen) and tripolyphosphate ions (Tpp) corrosion inhibitors. The epoxy coating (EP) embedded with Phen-Tpp@MTNs-PDDA (Phen-Tpp@MTNs-PDDA/EP) demonstrates superior self-healing properties and confers long-term protection on the metal substrate through the cooperative effect of Phen and Tpp.

pH-Responsive Graphene Oxide-Based 2D/3D Composite for Enhancing Anti-Corrosion Properties of Epoxy Coating.

The functionalized graphene oxide (GO)-based composites as fillers added into organic coatings are desired for realizing the longstanding corrosion protection of carbon steel. Here, the pH-responsive two-dimensional/three-dimensional (2D/3D) GO-based composite (ZIF-90-AAP/GO) was developed by environmentally friendly corrosion inhibitor 4-aminoantipyrine (AAP) anchored on the in situ growth of zeolite imidazolate framework-90 (ZIF-90) on the GO surface (ZIF-90/GO) through the Schiff base reaction. The active filler (ZIF-90-AAP/GO) was incorporated into an epoxy coating (EP) to obtain a high-performance self-healing coating on the surface of carbon steel.

Silicone-modified polyurea-interpenetrating polymer network fouling release coatings with excellent wear resistance property tailored to regulations.

The invasion of alien species via marine organisms attaching to the surfaces of ship hulls is a growing problem. A number of countries have introduced corresponding regulations to combat ship biofouling. One effective way to solve this problem is to apply a fouling release coating with excellent wear resistance.

Microstructure Turbulence Measurement in the Northern South China Sea from a Long-Range Hybrid AUV.

This study describes the development of a long-range hybrid autonomous underwater vehicle (AUV) for ocean turbulence measurement. It is a unique instrument, combining the characteristics of the conventional AUV and the buoyancy-driven glider, with a variety of flexible motion modes, such as cruise mode, glider mode, drift mode, and combination of multiple motion modes. The hybrid AUV was used for continuous turbulence measurement in the continental slope of the northern South China Sea in 2020.

Design and Motion Performance Analysis of Turbulent AUV Measuring Platform.

The use of a multi-functional autonomous underwater vehicle (AUV) as a platform for making turbulence measurements in the ocean is developed. The layout optimization of the turbulence package and platform motion performance are limitation problems in turbulent AUV design. In this study, the computational fluid dynamics (CFD) method has been used to determine the optimized layout position and distance of the shear probe integrated into an AUV.

Underwater gliders linear trajectory tracking: The experience breeding actor-critic approach.

This paper studies the underwater glider trajectory tracking in currents field. The objective is to ensure that trajectories fit to the straight target track. The underwater glider model is introduced to demonstrate the vehicle dynamic properties.

Three-dimensional heterostructured polypyrrole/nickel molybdate anchored on carbon cloth for high-performance flexible supercapacitors.

The urgent demands of energy storage for wearable electronics necessitates the development of flexible supercapacitors (FSCs). However, the service environment of portable/wearable devices requires supercapacitors to possess excellent mechanical properties to withstand harsh straining conditions, such as bending, rolling, and twisting. Hence, to develop a high-performance flexible supercapacitor (FSC) that possesses both superior electrochemical properties and remarkable mechanical capacities is still a formidable challenge.

Anti-Biofouling and Water-Stable Balanced Charged Metal Organic Framework-Based Polyelectrolyte Hydrogels for Extracting Uranium from Seawater.

Metal-organic frameworks (MOFs) are diffusely defined as a promising class of porous material for uranium extraction from seawater, but there are still challenges in their stability and anti-biofouling performance. Herein, a water-stable and anti-biofouling ZIF-67/SAP composite hydrogel was reported by the sequential processes of electrostatic interactions between the oppositely charged polymer, ionic gelation, and template growth of ZIF-67 crystals. Entanglement of positively charged polyethyleneimine (PEI) and negatively charged sodium alginate (SA) polymer chains provided external porosities, anti-biofouling properties, and mechanical support for the hydrogels and further reduced the possibility of ZIF-67 aggregation.

Ionic liquid combined with NiCoO/rGO enhances electrochemical oxygen sensing.

Ionic liquids are promising electrolytes for electrochemical gas sensors that have unique physicochemical properties such as negligible vapor pressure and high thermal stability. The modification of ionic liquid (IL) by combining metal oxide with reduced graphene oxide (rGO) is an effective method to improve its gas-sensing properties. In this study, the mesoporous structure of NiCoO/rGO is synthesized by simple one-step method, and the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF]) is mixed with it to form the composite material NiCoO/rGO/[BMIM][PF].

Layer-by-layer inkjet printing GO film and Ag nanoparticles supported nickel cobalt layered double hydroxide as a flexible and binder-free electrode for supercapacitors.

Inkjet printing is an attractive technique in the field of flexible electronics due to the direct writing, digital controls and non-contact operation process. In this work, we successfully printed graphite oxide and Ag nanoparticles on the substrate of flexible carbon cloth to form a flexible, conductive and hydrophilic layer, which could be used as a new substrate with an electron transport layer of large surface area. In addition, Ni-Co LDH nanosheets as the main active materials were synthesized for improving the electrochemical activity via a convenient electrochemical deposition method.

A Nonlinear Circuit Analysis Technique for Time-Variant Inductor Systems.

Time-variant inductors exist in many industrial applications, including sensors and actuators. In some applications, this characteristic can be deleterious, for example, resulting in inductive loss through eddy currents in motors designed for high efficiency operation. Therefore, it is important to investigate the electrical dynamics of systems with time-variant inductors.

Design and Performance Test of an Ocean Turbulent Kinetic Energy Dissipation Rate Measurement Probe.

Ocean turbulent kinetic energy dissipation rate is an essential parameter in marine environmental monitoring. Numerous probes have been designed to measure the turbulent kinetic energy dissipation rate in the past, and most of them utilize piezoelectric ceramics as the sensing element. In this paper, an ocean turbulent kinetic energy dissipation rate measurement probe utilizing a microelectromechanical systems (MEMS) piezoresistor as the sensing element has been designed and tested.

Polypyrrole/cobalt ferrite/multiwalled carbon nanotubes as an adsorbent for removing uranium ions from aqueous solutions.

A novel rod-like, dual-shell structural adsorbent of polypyrrole/cobalt ferrite/multiwalled carbon nanotubes (PPy/CoFe2O4/MWCNTs) was successfully synthesized by a hydrothermal method, which could easily separate uranium(vi) ions with an external magnetic field. The structure and morphology of PPy/CoFe2O4/MWCNTs were characterized by VSM, XRD, XPS TEM and FT-IR. The results proved that the dual-shell structure was obtained in which a shell of cobalt ferrite and polypyrrole formed around the MWCNTs core.

Synthesis, characterization and enhanced gas sensing performance of porous ZnCo2O4 nano/microspheres.

In recent years, spinel-type compounds have attracted great interest because of their gem-like qualities. However, little is known of their gas sensing properties. We report, in this paper, on a self-assembly method to prepare porous ZnCo2O4 (ZCO) nano/microspheres by a facile one-step solvothermal process and subsequent annealing.

Preparation of magnetic core-shell iron oxide@silica@nickel-ethylene glycol microspheres for highly efficient sorption of uranium(VI).

We report a facile approach for the formation of magnetic core-shell iron oxide@silica@nickel-ethylene glycol (Fe3O4@SiO2@Ni-L) microspheres. The structure and morphology of Fe3O4@SiO2@Ni-L are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and nitrogen sorption isotherm. The composite possesses a high specific surface area of 382 m(2) g(-1).

Thermal physical property-based fusion of geostationary meteorological satellite visible and infrared channel images.

Geostationary meteorological satellite infrared (IR) channel data contain important spectral information for meteorological research and applications, but their spatial resolution is relatively low. The objective of this study is to obtain higher-resolution IR images. One common method of increasing resolution fuses the IR data with high-resolution visible (VIS) channel data.