Preparation and Modeling of Graphene Bubbles to Obtain Strain-Induced Pseudomagnetic Fields.

It has been both theoretically predicted and experimentally demonstrated that strain can effectively modulate the electronic states of graphene sheets through the creation of a pseudomagnetic field (PMF). Pressurizing graphene sheets into bubble-like structures has been considered a viable approach for the strain engineering of PMFs. However, the bubbling technique currently faces limitations such as long manufacturing time, low durability, and challenges in precise control over the size and shape of the pressurized bubble.

Suppressed thermal transport in silicon nanoribbons by inhomogeneous strain.

Nanoscale structures can produce extreme strain that enables unprecedented material properties, such as tailored electronic bandgap, elevated superconducting temperature and enhanced electrocatalytic activity. While uniform strains are known to elicit limited effects on heat flow, the impact of inhomogeneous strains has remained elusive owing to the coexistence of interfaces and defects. Here we address this gap by introducing inhomogeneous strain through bending individual silicon nanoribbons on a custom-fabricated microdevice and measuring its effect on thermal transport while characterizing the strain-dependent vibrational spectra with sub-nanometre resolution.

Large and Pressure-Dependent Axis Piezoresistivity of Highly Oriented Pyrolytic Graphite near Zero Pressure.

The axis piezoresistivity is a fundamental and important parameter of graphite, but its value near zero pressure has not been well determined. Herein, a new method for studying the axis piezoresistivity of van der Waals materials near zero pressure is developed on the basis of scanning electron microscopy and finite element simulation. The axis piezoresistivity of microscale highly oriented pyrolytic graphite (HOPG) is found to show a large value of 5.

Toward Clean 2D Materials and Devices: Recent Progress in Transfer and Cleaning Methods.

Two-dimensional (2D) materials have tremendous potential to revolutionize the field of electronics and photonics. Unlocking such potential, however, is hampered by the presence of contaminants that usually impede the performance of 2D materials in devices. This perspective provides an overview of recent efforts to develop clean 2D materials and devices.

Conformability of flexible sheets on spherical surfaces.

Three-dimensional surface-conformable electronics is a burgeoning technology with potential applications in curved displays, bioelectronics, and biomimetics. Flexible electronics are notoriously difficult to fully conform to nondevelopable surfaces such as spheres. Although stretchable electronics can well conform to nondevelopable surfaces, they need to sacrifice pixel density for stretchability.

Pull-to-Peel of Two-Dimensional Materials for the Simultaneous Determination of Elasticity and Adhesion.

The flexible and clinging nature of ultrathin films requires an understanding of their elastic and adhesive properties in a wide range of circumstances from fabrications to applications. Simultaneously measuring both properties, however, is extremely difficult as the film thickness diminishes to the nanoscale. Here we address such difficulties through peeling by pulling thin films off from the substrates (we thus refer to it as "pull-to-peel").

Mechanical sensors based on two-dimensional materials: Sensing mechanisms, structural designs and wearable applications.

Compared with bulk materials, atomically thin two-dimensional (2D) crystals possess a range of unique mechanical properties, including relatively high in-plane stiffness and large bending flexibility. The atomic 2D building blocks can be reassembled into precisely designed heterogeneous composite structures of various geometries with customized mechanical sensing behaviors. Due to their small specific density, high flexibility, and environmental adaptability, mechanical sensors based on 2D materials can conform to soft and curved surfaces, thus providing suitable solutions for functional applications in future wearable devices.

Elastocapillary cleaning of twisted bilayer graphene interfaces.

Although layered van der Waals (vdW) materials involve vast interface areas that are often subject to contamination, vdW interactions between layers may squeeze interfacial contaminants into nanopockets. More intriguingly, those nanopockets could spontaneously coalesce into larger ones, which are easier to be squeezed out the atomic channels. Such unusual phenomena have been thought of as an Ostwald ripening process that is driven by the capillarity of the confined liquid.

Strengthening in Metal/Graphene Composites: Capturing the Transition from Interface to Precipitate Hardening.

A promising materials engineering method for improving the strength of crystalline materials is to add obstacles to dislocation motion that induce interface hardening (IH) or precipitate hardening (PH). In this study, molecular dynamics simulations are performed for Ni/graphene composites, revealing for the first time that graphene can strengthen the Ni matrix not only strictly via IH or PH but also through a continuous transition between the two. When graphene behaves like an interface, dislocation pileups form, whereas when it behaves as a precipitate, complex Orowan looping occurs by dislocation cross-slip.

Out-of-Plane Deformations Determined Mechanics of Vanadium Disulfide (VS) Sheets.

The rapid development of two-dimensional (2D) materials has significantly broadened the scope of 2D science in both fundamental scientific interests and emerging technological applications, wherein the mechanical properties play an indispensably key role. Nevertheless, particularly challenging is the ultrathin nature of 2D materials that makes their manipulations and characterizations considerably difficult. Herein, thanks to the excellent flexibility of vanadium disulfide (VS) sheets, their susceptibility to out-of-plane deformation is exploited to realize the controllable loading and enable the accurate measurements of mechanical properties.

Preparation of Twisted Bilayer Graphene via the Wetting Transfer Method.

Assembling monolayers into a bilayer system unlocks the rotational free degree of van der Waals (vdW) homo/heterostructure, enabling the building of twisted bilayer graphene (tBLG) which possesses novel electronic, optical, and mechanical properties. Previous methods for preparation of homo/heterstructures inevitably leave the polymer residue or hexagonal boron nitride (-BN) mask, which usually obstructs the measurement of intrinsic mechanical and surface properties of tBLG. Undoubtedly, to fabricate the designable tBLG with clean interface and surface is necessary but challenging.

Buckled AgNW/MXene hybrid hierarchical sponges for high-performance electromagnetic interference shielding.

The development of electromagnetic interference (EMI) shielding materials is moving forward towards being lightweight and showing high-performance. Here, we report on lightweight silver nanowire (AgNW)/MXene hybrid sponges featuring hierarchical structures that are fabricated by a combination of dip-coating and unidirectional freeze-drying methods. The commercial melamine formaldehyde sponges (MF), designed with a buckled structure, are chosen as the template for coating with the AgNW layer (BMF/AgNW).

Bending of Multilayer van der Waals Materials.

Out-of-plane deformation patterns, such as buckling, wrinkling, scrolling, and folding, formed by multilayer van der Waals materials have recently seen a surge of interest. One crucial parameter governing these deformations is bending rigidity, on which significant controversy still exists despite extensive research for more than a decade. Here, we report direct measurements of bending rigidity of multilayer graphene, molybdenum disulfide (MoS_{2}), and hexagonal boron nitride (hBN) based on pressurized bubbles.

"Cut-and-paste" method for the rapid prototyping of soft electronics.

Unlike wafer-based rigid electronics, soft electronics have many unique advantages including thinness, flexibility, stretchability, conformability, lightweight, large area, as well as low cost. As a result, they have demonstrated many emerging capabilities in healthcare devices, soft robotics, and human-machine interface. Instead of conventional microfabrication, there is an evergrowing interest in the freeform or digital manufacture of soft electronics.

Strain Engineering of 2D Materials: Issues and Opportunities at the Interface.

Triggered by the growing needs of developing semiconductor devices at ever-decreasing scales, strain engineering of 2D materials has recently seen a surge of interest. The goal of this principle is to exploit mechanical strain to tune the electronic and photonic performance of 2D materials and to ultimately achieve high-performance 2D-material-based devices. Although strain engineering has been well studied for traditional semiconductor materials and is now routinely used in their manufacturing, recent experiments on strain engineering of 2D materials have shown new opportunities for fundamental physics and exciting applications, along with new challenges, due to the atomic nature of 2D materials.

Elastomer-Free, Stretchable, and Conformable Silver Nanowire Conductors Enabled by Three-Dimensional Buckled Microstructures.

Many three-dimensional (3D) nanomaterial-based assemblies need incorporation with elastomers to attain stretchability-that also compromises their pristine advantages for functional applications. Here, we show the design of elastomer-free, highly deformable silver nanowire (AgNW) conductors through dip-coating AgNWs on a 3D polymeric scaffold and following a simple triaxial compression approach. The resulting 3D AgNW conductors exhibit good stability of resistance under multimodal deformation, such as stretching, compressing, and bending as well as comparable conductivity with those elastomer-based ones.

Interface-Governed Deformation of Nanobubbles and Nanotents Formed by Two-Dimensional Materials.

Nanoblisters such as nanobubbles and nanotents formed by two-dimensional (2D) materials have been extensively exploited for strain engineering purposes as they can produce self-sustained, nonuniform in-plane strains through out-of-plane deformation. However, deterministic measure and control of strain fields in these systems are challenging because of the atomic thinness and unconventional interface behaviors of 2D materials. Here, we experimentally characterize a simple and unified power law for the profiles of a variety of nanobubbles and nanotents formed by 2D materials such as graphene and MoS_{2} layers.

Engineering Surface Patterns with Shape Memory Polymers: Multiple Design Dimensions for Diverse and Hierarchical Structures.

Deterministic design of surface patterns has seen a surge of interests because of their wide applications in flexible and stretchable electronics, microfluidics, and optical devices. Recently, instability of bilayer systems has been extensively utilized by which micro-/nano-patterns of a film can be easily achieved through macroscopically deforming the underlying substrate. For a bilayer system with traditional thermostable substrates, the pattern morphology is only determined by initial strain mismatch of the two layers, and the realization of localized patterns appears to be particularly challenging because of the difficulties associated with manipulating inhomogeneous deformations.

Engineering the interface in mechanically responsive graphene-based films.

Due to their extraordinary mechanical properties, nanocarbon materials ( carbon nanotube and graphene) are attracting great interests in the field of nanocomposites. One unique feature in nanocarbon-based nanocomposites is their intrinsically rich interface, allowing them to adapt the microstructures in response to external loading and, in turn, to stiffen themselves. This mechanical behavior, called responsive stiffening, was usually observed in biological materials such as bones and muscles.

Mechanics of spontaneously formed nanoblisters trapped by transferred 2D crystals.

Layered systems of 2D crystals and heterostructures are widely explored for new physics and devices. In many cases, monolayer or few-layer 2D crystals are transferred to a target substrate including other 2D crystals, and nanometer-scale blisters form spontaneously between the 2D crystal and its substrate. Such nanoblisters are often recognized as an indicator of good adhesion, but there is no consensus on the contents inside the blisters.

Multiscale Hierarchical Design of a Flexible Piezoresistive Pressure Sensor with High Sensitivity and Wide Linearity Range.

Flexible piezoresistive pressure sensors have been attracting wide attention for applications in health monitoring and human-machine interfaces because of their simple device structure and easy-readout signals. For practical applications, flexible pressure sensors with both high sensitivity and wide linearity range are highly desirable. Herein, a simple and low-cost method for the fabrication of a flexible piezoresistive pressure sensor with a hierarchical structure over large areas is presented.

Extremely Vivid, Highly Transparent, and Ultrathin Quantum Dot Light-Emitting Diodes.

Displaying information on transparent screens offers new opportunities in next-generation electronics, such as augmented reality devices, smart surgical glasses, and smart windows. Outstanding luminance and transparency are essential for such "see-through" displays to show vivid images over clear background view. Here transparent quantum dot light-emitting diodes (Tr-QLEDs) are reported with high brightness (bottom: ≈43 000 cd m , top: ≈30 000 cd m , total: ≈73 000 cd m at 9 V), excellent transmittance (90% at 550 nm, 84% over visible range), and an ultrathin form factor (≈2.

Measuring Interlayer Shear Stress in Bilayer Graphene.

Monolayer two-dimensional (2D) crystals exhibit a host of intriguing properties, but the most exciting applications may come from stacking them into multilayer structures. Interlayer and interfacial shear interactions could play a crucial role in the performance and reliability of these applications, but little is known about the key parameters controlling shear deformation across the layers and interfaces between 2D materials. Herein, we report the first measurement of the interlayer shear stress of bilayer graphene based on pressurized microscale bubble loading devices.

Construction of Small-Diameter Vascular Graft by Shape-Memory and Self-Rolling Bacterial Cellulose Membrane.

Bacterial cellulose (BC) membranes with shape-memory properties allow the rapid preparation of artificial small-diameter blood vessels when combined with microfluidics-based patterning with multiple types of cells. Lyophilization of a wet multilayered rolled BC tube endows it with memory to recover its tubular shape after unrolling. The unrolling of the BC tube yields a flat membrane, and subsequent patterning with endothelial cells, smooth muscle cells, and fibroblast cells is carried out by microfluidics.