The Impact of Metal Centers in the M-MOF-74 Series on Formic Acid Production.

The confinement effect of porous materials on the thermodynamical equilibrium of the CO hydrogenation reaction presents a cost-effective alternative to transition metal catalysts. In metal-organic frameworks, the type of metal center has a greater impact on the enhancement of formic acid production than the scale of confinement resulting from the pore size. The M-MOF-74 series enables a comprehensive study of how different metal centers affect HCOOH production, minimizing the effect of pore size.

Poly(Vinylidene Fluoride-co-Hexafluoropropylene) Films Filled in Iron Nanoparticles for Infrared Shielding Applications.

In order to use the infrared (IR) radiation shielding materials, they should take a form of thin film coatings deposited on glass/polymer substrates or be used as fillers of glass/polymer. The first approach usually suffers from several technological problems. Therefore, the second strategy gains more and more attention.

Solubility of CO in Aqueous Formic Acid Solutions and the Effect of NaCl Addition: A Molecular Simulation Study.

There is a growing interest in the development of routes to produce formic acid from CO, such as the electrochemical reduction of CO to formic acid. The solubility of CO in the electrolyte influences the production rate of formic acid. Here, the dependence of the CO solubility in aqueous HCOOH solutions with electrolytes on the composition and the NaCl concentration was studied by Continuous Fractional Component Monte Carlo simulations at 298.

Monotonic and Creep Studies on the Pull-Through Resistance of Laminated Glass with Locally Embedded Steel Mesh.

The paper deals with the phenomenon of post-breakage capacity in point-fixed laminated glass elements and reports the results of an ongoing research project aimed at developing a reinforced point-fixed laminated glass element with locally embedded steel mesh and increased post-breakage capacity. The work involved monotonic and creep studies on the pull-through resistance in a custom-made experimental setup. A total of 12 test series and 48 specimens were tested, including reference and reinforced samples.

New Features of the Open Source Monte Carlo Software Brick-CFCMC: Thermodynamic Integration and Hybrid Trial Moves.

We present several new major features added to the Monte Carlo (MC) simulation code Brick-CFCMC for phase- and reaction equilibria calculations (https://gitlab.com/ETh_TU_Delft/Brick-CFCMC). The first one is thermodynamic integration for the computation of excess chemical potentials (μ).