Herein, we carefully investigated the Fe doping effects on the structure and electron distribution of CrO nanoparticles using X-ray diffraction analysis (XRD), maximum entropy method (MEM), and density functional theory (DFT) calculations. We showed that increasing the Fe doping induces an enlargement in the axial ratio of /, which is associated with an anisotropic expansion of the unit cell. We found that as Fe replaces Cr in the CrO lattice, it caused a higher interaction between the metal 3 states and the oxygen 2 states, which led to a slight increase in the Cr/Fe-O1 bond length followed by an opposite effect for the Cr/Fe-O2 bonds.
View Article and Find Full Text PDFThe composition, structural features, surface morphology, roughness parameters, particle size, and magnetic features of nanostructured Fe-Co-Ni deposits manufactured on conducting indium tin oxide-coated glasses at various electrolyte pH values are studied. The deposit produced at low electrolyte pH contains slightly higher Fe and Co contents but lower Ni content compared to deposits fabricated at high pH values. Further composition analysis confirms that the reduction rates of Fe and Co are higher than the Ni reduction rate.
View Article and Find Full Text PDFIn this research, the structural properties, surface morphology, and magnetic characteristics of nanostructured ternary ferromagnetic alloys grown by a cost-effective and effortless two-step electrochemical deposition method on indium tin oxide (ITO) substrates with and without a galvanostatic pretreatment process (GPP) were examined. The GPP was applied at various pretreatment current densities (PCDs) such as -10, -20, and - 30 mA/cm . The effect of the PCD on the Ni, Co, and Fe contents is found to be insignificant and all resultant Ni-Co-Fe thin films show an abnormal co-deposition.
View Article and Find Full Text PDFPolypyrrole (PPy) films doped with molybdate and salicylate have been successfully electropolymerized on low carbon steel in aqueous solutions containing both molybdate and salicylate in a one-step process that did not require any pre-treatment of the steel substrate. Salicylate-doped PPy films were synthesized in the same way for comparison. The steel surface was rapidly inhibited and the PPy-based films were formed on it easily.
View Article and Find Full Text PDFThe California Bearing Ratio (CBR) is an important index for evaluating the bearing capacity of pavement subgrade materials. In this research, random subspace optimization-based hybrid computing models were trained and developed for the prediction of the CBR of soil. Three models were developed, namely reduced error pruning trees (REPTs), random subsurface-based REPT (RSS-REPT), and RSS-based extra tree (RSS-ET).
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