We show that ultra-cold polar diatomic or linear molecules, oriented in an external electric field and mutually coupled by dipole-dipole interactions, can be used to realize the exact Heisenberg XYZ, XXZ and XY models without invoking any approximation. The two lowest lying excited pendular states coupled by microwave or radio-frequency fields are used to encode the pseudo-spin. We map out the general features of the models by evaluating the models constants as functions of the molecular dipole moment, rotational constant, strength and direction of the external field as well as the distance between molecules.
View Article and Find Full Text PDFPhys Chem Chem Phys
April 2022
In electronic structure calculations, the correlation energy is defined as the difference between the mean field and the exact solution of the non relativistic Schrödinger equation. Such an error in the different calculations is not directly observable as there is no simple quantum mechanical operator, apart from correlation functions, that correspond to such quantity. Here, we use the dimensional scaling approach, in which the electrons are localized at the large-dimensional scaled space, to describe a geometric picture of the electronic correlation.
View Article and Find Full Text PDFCollecting and removing ocean plastics can mitigate their environmental impacts; however, ocean cleanup will be a complex and energy-intensive operation that has not been fully evaluated. This work examines the thermodynamic feasibility and subsequent implications of hydrothermally converting this waste into a fuel to enable self-powered cleanup. A comprehensive probabilistic exergy analysis demonstrates that hydrothermal liquefaction has potential to generate sufficient energy to power both the process and the ship performing the cleanup.
View Article and Find Full Text PDFWe employ a simple and accurate dimensional interpolation formula for the shapes of random walks at = 3 and = 2 based on the analytically known solutions at both limits = ∞ and = 1. The results obtained for the radius of gyration of an arbitrary shaped object have about 2% error compared with accurate numerical results at = 3 and = 2. We also calculated the asphericity for a three-dimensional random walk using the dimensional interpolation formula.
View Article and Find Full Text PDFOur 1. Prologue section applauds some previous celebrations of Peter's inspiring ebullient adventures, including a remarkable new book by Giorgio Benedek and Peter on investigations of surfaces by helium beam scattering. The next sections treat 2.
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