The role of water mobility on water-responsive actuation of silk.

Biological water-responsive materials that deform with changes in relative humidity have recently demonstrated record-high actuation energy densities, showing promise as high-performance actuators for various engineering applications. However, there is a lack of theories capable of explaining or predicting the stress generated during water-responsiveness. Here, we show that the nanoscale confinement of water dominates the macroscopic dehydration-induced stress of the regenerated silk fibroin.

Water treatment by cavitation: Understanding it at a single bubble - bacterial cell level.

Cavitation is a potentially useful phenomenon accompanied by extreme conditions, which is one of the reasons for its increased use in a variety of applications, such as surface cleaning, enhanced chemistry, and water treatment. Yet, we are still not able to answer many fundamental questions related to efficacy and effectiveness of cavitation treatment, such as: "Can single bubbles destroy contaminants?" and "What precisely is the mechanism behind bubble's cleaning power?". For these reasons, the present paper addresses cavitation as a tool for eradication and removal of wall-bound bacteria at a fundamental level of a single microbubble and a bacterial cell.

Aromatic Zipper Topology Dictates Water-Responsive Actuation in Phenylalanine-Based Crystals.

Water-responsive (WR) materials that reversibly deform in response to relative humidity (RH) changes are gaining increasing interest for their potential in energy harvesting and soft robotics applications. Despite progress, there are significant gaps in the understanding of how supramolecular structure underpins the reconfiguration and performance of WR materials. Here, three crystals are compared based on the amino acid phenylalanine (F) that contain water channels and F packing domains that are either layered (F), continuously connected (phenylalanyl-phenylalanine, FF), or isolated (histidyl-tyrosyl-phenylalanine, HYF).

Enhanced water-responsive actuation of porous silk.

silk with a nanoscale porous architecture significantly deforms in response to changes in relative humidity. Despite the increasing amount of water adsorption and water-responsive strain with increasing porosity of the silk, there is a range of porosities that result in silk's optimal water-responsive energy density at 3.1 MJ m.

Investigation of hydrodynamic cavitation induced reactive oxygen species production in microchannels via chemiluminescent luminol oxidation reactions.

Hydrodynamic cavitation was evaluated for its reactive oxygen species production in several convergent-divergent microchannel at the transition from micro to milli scale. Channel widths and heights were systematically varied to study the influence of geometrical parameters at the transitory scale. A photomultiplier tube was used for time-resolved photon detection and monitoring of the chemiluminescent luminol oxidation reactions, allowing for a contactless and in situ quantization of reactive oxygen species production in the channels.