The structuring of water at soft solid surfaces remains an area of great interest to colloid science as a whole and has many applications in relation to colloid stability, foams, and wetting films as well as being central to membrane separations. Quantitatively calculating the structural components of thin layers of water and the interaction forces of hydrated molecules with the surface of pores through a layer of water having modified structure is one of the most important challenges in the physics of surface phenomenon. In this paper these effects are reviewed and discussed in relation to the confines of a capillary pore.
View Article and Find Full Text PDFThe present study demonstrates the high potential for the application of a novel self assembled positively charged nanofiltration membrane, PA6DT-C, in processes such as the recovery of valuable cationic macromolecules in the bioprocess and pharmaceutical industries or removal of multi-valent cations such as dyes and heavy metals in the paper and pulp, textiles, nuclear, and automotive industries. The nanofiltration membrane, prepared in this laboratory, is further characterised and then tested for the removal and recovery of Methylene Blue from a synthetic dye house wastewater. The characterisation process involved the construction of a rejection profile for NaCl over a wide range of pH and concentration, which illustrates that the optimal process conditions for the removal of small cations using this membrane is in the region pH <8.
View Article and Find Full Text PDFA review of the fabrication processes currently available to produce positively charged nanofiltration membranes has been conducted. The review highlights that there are few membranes and studies currently available. The preparation of a novel positively charged nanofiltration membrane is also described.
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