Publications by authors named "D M Schwertfeger"

Increased use of nano-cerium oxide (nCeO) in an array of industrial applications has raised environmental concerns due to potential increased loadings to the soil environment. This research investigated the potential adverse effects of nCeO (10-30 nm) on the soil microbial community in two exposure scenarios: direct application to soil, and indirect application to soil through chemical spiking of biosolids, followed by mixing into soil. Total Ce in test soils without, and with biosolids amendment, ranged from 44 to 770, and 73 to 664 mg Ce kg soil, respectively.

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The growing use of silver nanoparticles (AgNPs) in personal care products and clothing has increased their concentrations in wastewater and subsequently in sludge raising concerns about their fate and toxicity during wastewater treatment and after land application of sludge. This research investigated the fate and removal of AgNPs during chemical conditioning of anaerobically digested sludge and their impact on soil bacteria and health after land application. Ferric chloride (FeCl), alum (Al (SO) • (14-18) HO), and synthetic (polyacrylamide) polymer were used for sludge conditioning.

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Article Synopsis
  • The research focused on the effects of copper oxide nanoparticles (nCuO) in soil, using earthworms and springtails to assess toxicity and bioaccumulation, comparing nCuO with soluble copper sulfate (CuSO).
  • Toxicity levels were found to be similar between nCuO and CuSO for springtails, but earthworm reproduction was significantly impacted by both forms, indicating particle dissolution in soil likely drives toxicity.
  • The study highlights that current risk assessment methods for trace metals can apply to nCuO, yet emphasizes the importance of particle dissolution rates in varying soil conditions when evaluating environmental impact.
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This study represents a holistic approach in assessing the effects of copper oxide nanoparticles (nCuO) on microbial health and community structure in soil amended with municipal biosolids. The biosolids were amended with nCuO (<50 nm) and mixed into a sandy loam soil at measured Cu concentrations of 27, 54, 123, 265 and 627 mg Cu kg soil. A suite of tests were used to assess the potential impact of nCuO on microbial growth, activity, and diversity.

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The use of engineered silver nanoparticles (AgNPs) is widespread, with expected release to the terrestrial environment through the application of biosolids onto agricultural lands. The toxicity of AgNPs and silver nitrate (AgNO ; as ionic Ag ) to plant (Elymus lanceolatus and Trifolium pratense) and soil invertebrate (Eisenia andrei and Folsomia candida) species was assessed using Ag-amended biosolids applied to a natural sandy loam soil. Bioavailable Ag in soil samples was estimated using an ion-exchange technique applied to KNO soil extracts, whereas exposure to dispersible AgNPs was verified by single-particle inductively coupled plasma-mass spectrometry and transmission electron microscopy-energy dispersive X-ray spectroscopy analysis.

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